Skip to main content
Log in

Effect of doping concentration and annealing temperature on threshold voltages of bipolar resistive switching in Mn-doped BiFeO3 films

  • Original Paper: Sol-gel and hybrid materials for dielectric, electronic, magnetic and ferroelectric applications
  • Published:
Journal of Sol-Gel Science and Technology Aims and scope Submit manuscript

Abstract

Nonvolatile bipolar resistive switching has been investigated in Mn-doped BiFeO3 thin films fabricated by sol–gel method. Based on the analyses of X-ray diffractometer and X-ray photoelectron spectroscopy, the threshold voltages for forming and set operations in bipolar resistive switching, which are found to depend on Mn doping concentration and annealing temperature, can be ascribed to the variation of oxygen vacancy concentration and grain size. Therefore, the modulated ionic oxygen vacancy conductivity has been suggested to play a pivotal role in the resistive switching of Mn-doped BiFeO3 thin films.

Graphical Abstract

The forming and set voltages of resistive switching depend on doping concentration and annealing temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Chen WJ, Zheng Y, Wang B (2014) Pinning effects of dislocations on vortex domain structure in ferroelectric nanodots. Appl Phys Lett 104(22):222912

    Article  Google Scholar 

  2. Wu CM, Chen WJ, Zheng Y, Ma DC, Wang B, Liu JY, Woo CH (2014) Controllability of vortex domain structure in ferroelectric nanodot: fruitful domain patterns and transformation paths. Sci Rep 4:3946

    Google Scholar 

  3. Kuang DH, Tang P, Yang SH, Zhang YL (2015) Effect of annealing temperatures on the structure and leakage mechanisms of BiFeO3 thin films prepared by the sol–gel method. J Sol-Gel Sci Technol 73(2):410–416

    Article  Google Scholar 

  4. Ghafoor I, Siddiqi SA, Shahid Atiq S, Riaz S, Naseem S (2015) Sol–gel synthesis and investigation of structural, electrical and magnetic properties of Pb doped La0.1Bi0.9FeO3 multiferroics. J Sol-Gel Sci Technol 74(2):352–356

    Article  Google Scholar 

  5. Kim JW, Raghavan CM, Kim SS (2015) Structural and electrical properties of 0.7BiFeO3–0.3CaTiO3 solid solution thin films deposited from solutions. J Sol-Gel Sci Technol 76(3):693–698

    Article  Google Scholar 

  6. Luo JM, Chen SH, Bu SL, Wen JP (2014) Resistive switching and Schottky diode-like behaviors in Pt/BiFeO3/ITO devices. J Alloys Compd 601:100–103

    Article  Google Scholar 

  7. Kim WH, Son JY, Jang HM (2014) Confinement of ferroelectric domain-wall motion at artificially formed conducting-nanofilaments in epitaxial BiFeO3 thin films. ACS Appl Mater Interfaces 6(9):6346–6350

    Article  Google Scholar 

  8. Shuai Y, Zhou S, Bürger D, Helm M, Schmidt H (2011) Nonvolatile bipolar resistive switching in Au/BiFeO3/Pt. J Appl Phys 109(12):124117

    Article  Google Scholar 

  9. Yang CH, Seidel J, Kim SY, Rossen PB, Yu P, Gajek M, Chu YH, Martin LW, Holcomb MB, He Q, Maksymovych P, Balke N, Kalinin SV, Baddorf AP, Basu SR, Scullin ML, Ramesh R (2009) Electric modulation of conduction in multiferroic Ca-doped BiFeO3 films. Nat Mater 8(6):485–493

    Article  Google Scholar 

  10. Yin K, Li M, Liu Y, He C, Zhuge F, Chen B, Lu W, Pan X, Li RW (2010) Resistance switching in polycrystalline BiFeO3 thin films. Appl Phys Lett 97(4):042101

    Article  Google Scholar 

  11. Huang JZ, Wang Y, Lin Y, Li M, Nan CW (2009) Effect of Mn doping on electric and magnetic properties of BiFeO3 thin films by chemical solution deposition. J Appl Phys 106(6):063911

    Article  Google Scholar 

  12. Riaz S, Shah SMH, Akbar A, Atiq S, Naseem S (2015) Effect of Mn doping on structural, dielectric and magnetic properties of BiFeO3 thin films. J Sol-Gel Sci Technol 74(2):329–339

    Article  Google Scholar 

  13. Luo JM, Lin SP, Zheng Y, Wang B (2012) Nonpolar resistive switching in Mn-doped BiFeO3 thin films by chemical solution deposition. Appl Phys Lett 101(6):062902

    Article  Google Scholar 

  14. Luo JM, Chen RQ, Lin SP (2014) The physical nature of bipolar resistive switching in Pt/BiFe0.95Mn0.05O3/Pt memory devices. Phys Status Solidi A 211(1):191–194

    Article  Google Scholar 

  15. Qi X, Dho J, Tomov R, Blamire MG, MacManus-Driscoll JL (2005) Greatly reduced leakage current and conduction mechanism in aliovalent-ion-doped BiFeO3. Appl Phys Lett 86(6):062903

    Article  Google Scholar 

  16. Chen X, Zhang H, Ruan K, Shi W (2012) Annealing effect on the bipolar resistive switching behaviors of BiFeO3 thin films on LaNiO3-buffered Si substrates. J Alloys Compd 529:108–112

    Article  Google Scholar 

  17. Zhu X, Zhuge F, Li M, Yin K, Liu Y, Zuo Z, Chen B, Li RW (2011) Microstructure dependence of leakage and resistive switching behaviours in Ce-doped BiFeO3 thin films. J Phys D Appl Phys 44(41):415104

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the Natural Science Foundation of Guangdong Province (No. 2014A030310410) and the Research Foundation from Department of Education of Guangdong Province (No. 314B0109). The author greatly acknowledges Prof. B. Wang and Prof. Y. Zheng (Sun Yat-Sen University) for valuable suggestions and discussions.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jinming Luo.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Luo, J., Zhang, H., Wen, J. et al. Effect of doping concentration and annealing temperature on threshold voltages of bipolar resistive switching in Mn-doped BiFeO3 films. J Sol-Gel Sci Technol 78, 166–170 (2016). https://doi.org/10.1007/s10971-015-3916-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10971-015-3916-9

Keywords

Navigation