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Determination of excess molar enthalpies for the ternary system p-xylene+octane+diethyl carbonate

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Abstract

Excess molar enthalpies, H E, for the binary mixtures {p-xylene+(1–x) octane}, {x p-xylene+(1–x) diethyl carbonate}, {x octane+(1–x) diethyl carbonate} and the corresponding ternary system {x 1 p-xylene+x 2 octane+(1–x 1–x 2) diethyl carbonate} have been measured by using a Calvet microcalorimeter at 298.15 K under atmospheric pressure. The experimental H E values are all positive for the binary and ternary mixtures over the entire composition range.

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Authors and Affiliations

  1. Departamento de Física Aplicada, Campus Universitario Sur, Universidade de Santiago, Santiago de Compostela, Spain, 15782

    P. V. Verdes & M. I. Paz Andrade

  2. Departamento de Física Aplicada, Facultad de Ciencias del Mar, Campus As Lagoas- Marcosende, Universidade de Vigo, Vigo, Spain, 36310

    M. M. Mato & J. L. Legido

  3. Departamento de Física, Facultade de Ciencias, Universidade de A Coruña, A Coruña, Spain, 15071

    E. Jiménez

Authors
  1. P. V. Verdes
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  2. M. M. Mato
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  3. J. L. Legido
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  4. E. Jiménez
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  5. M. I. Paz Andrade
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Correspondence to M. I. Paz Andrade.

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Verdes, P.V., Mato, M.M., Legido, J.L. et al. Determination of excess molar enthalpies for the ternary system p-xylene+octane+diethyl carbonate. J Therm Anal Calorim 88, 583–586 (2007). https://doi.org/10.1007/s10973-006-8229-3

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  • DOI: https://doi.org/10.1007/s10973-006-8229-3

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