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Critical assessment of thermodynamic properties of perovskite-type cesium lead chloride CsPbCl3

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Abstract

The results of thermochemical study of the CsPbCl3 formation thermodynamics available in literature were critically evaluated by comparison with those calculated from the temperature dependence of EMF of galvanic cells involving CsPbCl3 as well as with the newly obtained solution calorimetric data. The origin of the discrepancy between the values of standard formation enthalpy reported by different scientific groups was identified. Redetermined solution enthalpy of CsPbCl3 in dimethyl sulfoxide allowed correcting the earlier reported value of the standard formation enthalpy of CsPbCl3. As a result, the following consistent set of the thermodynamic functions for CsPbCl3 was obtained: \({\Delta }_{\mathrm{f}}{H}_{298}^{^\circ }\) = (–810.3 ± 0.4) kJ mol−1, \({S}_{298}^{^\circ }\) = (270.1 ± 4.3) J mol−1 K−1.

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Acknowledgements

This work was supported by the Russian Science Foundation (Grant No. 18-73-10059).

Funding

This work was supported by the Russian Science Foundation (Grant No. 18–73-10059).

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Authors and Affiliations

  1. Institute of Natural Sciences and Mathematics, Ural Federal University, 19 Mira St., Ekaterinburg, Russia, 620002

    D. S. Tsvetkov, M. O. Mazurin, V. V. Sereda, I. L. Ivanov, D. A. Malyshkin & A. Yu. Zuev

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  1. D. S. Tsvetkov
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  2. M. O. Mazurin
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  3. V. V. Sereda
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  4. I. L. Ivanov
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  6. A. Yu. Zuev
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Tsvetkov, D.S., Mazurin, M.O., Sereda, V.V. et al. Critical assessment of thermodynamic properties of perovskite-type cesium lead chloride CsPbCl3. J Therm Anal Calorim 147, 12661–12667 (2022). https://doi.org/10.1007/s10973-022-11480-8

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