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Formation of Metastable Aluminides in Alloys of Al – Hf – Sc (Ti) Systems

  • 16th INTERNATIONAL IUPAC CONFERENCE ON THE CHEMISTRY OF HIGH-TEMPERATURE MATERIALS
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Metal Science and Heat Treatment Aims and scope

The methods of optical and scanning electron microscopy and x-ray spectrum microanalysis are used to study and to compare the special features of formation of metastable trialuminides under rapid crystallization of superheated melts of the Al – Hf – Sc and Al – Hf – Ti systems. Heating of such melts by over 100°C above the liquidus temperature yields Aln(Hf1–xScx) and Aln(Hf1–x Tix) aluminides with a cubic lattice of structural type L12.

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Notes

  1. Here and below in the paper the content of elements is given is atomic percent.

References

  1. M. E. Fine, “Precipitation hardening of aluminum alloys,” Metall. Trans. A, 6(4), 625 – 630 (1975).

    Article  Google Scholar 

  2. K. E. Knipling, D. C. Dunald, and D. N. Seidman, “Nucleation and precipitation strengthening in dilute Al – Ti and Al – Zr alloys,” Metall. Mater. Trans. A, 38A, 2552 – 2563 (2007).

    Article  CAS  Google Scholar 

  3. K. E. Knipling, D. C. Dunald, and D. N. Seidman, “Precipitation evolution in Al – Zr and Al – Zr – Ti alloys during isothermal aging at 375 – 425°C,” Acta Mater., 56, 114 – 127 (2008).

  4. K. E. Knipling, D. C. Dunald, and D. N. Seidman, “Precipitation evolution in Al – Zr and Al – Zr – Ti alloys during aging at 450 – 600°C,” Acta Mater., 56, 1182 – 1195 (2008).

  5. K. E. Knipling, D. C. Dunald, and D. N. Seidman, “Precipitation evolution in Al – 0.1Sc, Al – 0.1Zr and Al – 0.1Sc – 0.1Zr (at.%) alloys during isochronal aging,” Acta Mater., 58, 5184 – 5195 (2010).

    Article  CAS  Google Scholar 

  6. V. V. Zakharov, “About alloying of aluminum alloys with transition metals,” Metalloved. Term. Obrab. Met., No. 2, 3 – 8 (2017).

  7. Y. Du, Y. A. Chang, B. Huang, et al., “Diffusion coefficients of some solutes in fcc and liquid Al: critical evaluation and correlation,” Mater. Sci. Eng. A, 363(1 – 2), 140 – 151 (2003).

  8. J. Royset and N. Ryum, “Scandium in aluminum alloys,” Int. Mater. Rev., 50(1), 19 – 44 (2005).

    Article  CAS  Google Scholar 

  9. A. E. Carlsson and P. J. Meschter, “Relative stability of Ll2 , D022 and D023 structures in MAl3 compounds,” J. Mater. Res., 4(5), 1060 – 1063 (1989).

  10. G. Ghosh and M. Asta, “First-principles calculation of structural energetics of Al – TM (MT = Ti, Zr, Hf) intermetallics,” Acta Mater., 53, 3225 – 3252 (2005).

    Article  CAS  Google Scholar 

  11. S. Srinivasan, P. B. Desch, and R. B. Schwarz, “Metastable phases in the Al3 X (X = Ti, Zr, and Hf) intermetallic system,” Scr. Metall. Mater., 25(11), 2513 – 2516 (1991).

    Article  CAS  Google Scholar 

  12. I. G. Brodova, V. M. Zamyatin, P. S. Poppel, et al., “Conditions of formation of metastable phases in crystallization of Al – Zr alloys,” Rasplavy, 2(6), 23 – 27 (1988).

    CAS  Google Scholar 

  13. I. G. Brodova, I. V. Polents, V. O. Esin, and B. M. Lobov, “Laws of formation of cast structure of supercooled Al – Ti alloys,” Fiz. Met. Metalloved., No. 1, 84 – 89 (1992).

  14. A. F. Norman and P. Tsakiropoulos, “Rapid solidification of Al – Hf alloys — solidification, microstructures and decomposition of solid-solutions,” Int. J. Rapid Solid., 6(3 – 4), 185 – 213 (1991).

  15. P. Malek, M. Janecek, B. Smola, et al., “Structure and properties of rapidly solidified Al – Zr – Ti alloys,” J. Mater. Sci., 35, 2625 – 2633 (2000).

    Article  CAS  Google Scholar 

  16. E. A. Popova, A. B. Shubin, P. V. Kotenkov, et al., “Al – Ti – Zr master alloys: structure formation,” Russian Metallurgy (Metally), No. 5, 357 – 361 (2012).

  17. E. A. Popova, P. V. Kotenkov, E. A. Pastushkov, and A. B. Shubin, “Master alloys Al – Sc – Zr, Al – Sc – Ti, and Al – Ti – Zr: their manufacture, composition, and structure,” Russian Metallurgy (Metally), No. 8, 590 – 594 (2013).

  18. E. A. Popova, P. V. Kotenkov, and A. B. Shubin, “Formation of aluminides with Ll2 cubic lattice in alloys of the Al – Zr – Y, Al – Ti – Y systems,” Metalloved. Term. Obrab. Met., No. 9, 14 – 18 (2018).

  19. J. L. Murray, A. J. McAlister, and D. J. Kahan, “The Al – Hf (aluminum–hafnium) system,” J. Phase Equil., 19(4), 376 – 379 (1998).

    Article  CAS  Google Scholar 

  20. H. W. Kerr, J. Cisse, and G. F. Boiling, “On equilibrium and nonequilibrium peritectic transformation,” Acta Metall., 22, 677 – 686 (1974).

    Article  CAS  Google Scholar 

  21. J. L. Murray, “The Al – Sc (aluminum–scandium) system,” J. Phase Equil., 19(4), 380 – 384 (1998).

    Article  CAS  Google Scholar 

  22. E. A. Popova, P. V. Kotenkov, A. B. Shubin, and E. A. Pastukhov, “Special features of structure of Al – Hf – Sc master alloys,” Izv. Vysh. Ucheb. Zaved., Tsvet. Metall., No. 5, 69 – 74 (2017).

  23. E. A. Popova, P. V. Kotenkov, and A. B. Shubin, “Formation of metastable aluminides in alloys of the Al – Hf – Ti system,” Tsvet. Met., No. 11(899), 65 – 70 (2017).

  24. O. Setiukov and I. Fridlyander, “Peculiarities of Ti dendritic segregation in aluminum alloys,” in: Aluminum Alloys: Their Physical and Mechanical Properties, Mater. Sci. Forum, France (1996), pp. 195 – 200.

  25. H. Hallem, B. Forbord, and K. Marthinsen, “An investigation of cast structures in Al – Hf – (Sc) – (Zr) alloys and their subsequent effect on recrystallization resistance and cold rolling,” Mater. Forum, 28, 240 – 245 (2004).

    CAS  Google Scholar 

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The work has been performed within State Assignment to IMET UrO RAN and with the use of the equipment of the “Ural-M” Collective Use Center.

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Correspondence to P. V. Kotenkov.

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Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 12, pp. 38 – 42, December, 2019.

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Popova, E.A., Kotenkov, P.V. & Gilev, I.O. Formation of Metastable Aluminides in Alloys of Al – Hf – Sc (Ti) Systems. Met Sci Heat Treat 61, 782–786 (2020). https://doi.org/10.1007/s11041-020-00500-9

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  • DOI: https://doi.org/10.1007/s11041-020-00500-9

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