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Optically induced anisotropy and electrooptics in ferroic organic nanocomposites

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Abstract

The occurrence of linear electrooptics and optical anisotropy is observed in the ferroic crystals \([\hbox {NH}_{2}(\hbox {C}_{2}\hbox {H}_{5})_{2}]_{2} \hbox {CuCl}_{4 }\) embedded into polymethylmethacrylate polymer matrix. The studies were performed for the optically treated bulk crystals and the large-size nanocrystals (with sizes higher than 50 nm) embedded into the polymer matrix. The specimens were both in a form of bulk as well as in the form of the composite films. To understand the mechanisms giving the principal role to the effect we have performed polarized absorption measurements for the samples treated in the external dc-electric field and bicolour 532 nm/1,064 nm laser treatments. The behaviour of the birefringence and of the linear electrooptics coefficients were studied within a temperature range covering the incommensurate phase existence.

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Acknowledgments

This work was performed within a framework of National Grant and the authors wish to thank the Ministry of Science and Higher Education (Grants No. IP2011 039671) for financial support.

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Correspondence to G. Myronchuk.

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Ozga, K., Lakshminarayana, G., Szota, M. et al. Optically induced anisotropy and electrooptics in ferroic organic nanocomposites. Opt Quant Electron 45, 1115–1124 (2013). https://doi.org/10.1007/s11082-013-9728-7

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  • DOI: https://doi.org/10.1007/s11082-013-9728-7

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