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High performance of carbon dioxide adsorption of mesoporous mordenite synthesized in the presence of N,N-dimethylaniline

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Abstract

Mesoporous Na-mordenite zeolite was successfully synthesized by soft templating method in the presence of N,N-dimethylaniline and characterized using several techniques (XRD, SEM, BET, FTIR, and TG/dTG). The prepared material then underwent ion exchange with two alkali metal cations (K+, Cs+). Intracrystalline diffusion and alkalinity of zeolites were attributed to high adsorption capacities of CO2. Carbon dioxide capturing capacity increased in the sequence Cs-MOR > K-MOR > Na-MOR. Langmuir and Freundlich models were used to describe the adsorption behavior of CO2 over alkali-mordenite samples, and good agreement with experimental data was found.

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Authors and Affiliations

  1. Laboratoire de chimie des matériaux, Département de Chimie, Faculté des Sciences Exactes et Appliquées, Université d’Oran 1 Ahmed Ben Bella, El M’naouar, BP: 1524, Oran, Algérie

    Boumediéne Bensafi, Nadjat Chouat & Fatiha Djafri

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  1. Boumediéne Bensafi
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  2. Nadjat Chouat
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  3. Fatiha Djafri
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Correspondence to Boumediéne Bensafi.

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Bensafi, B., Chouat, N. & Djafri, F. High performance of carbon dioxide adsorption of mesoporous mordenite synthesized in the presence of N,N-dimethylaniline. Res Chem Intermed 43, 7443–7456 (2017). https://doi.org/10.1007/s11164-017-3085-2

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  • DOI: https://doi.org/10.1007/s11164-017-3085-2

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