Abstract
The reaction of NiCl2 with the chiral pentadentate nitrogen-containing ligand H2L derived from the natural terpenoid (+)-3-carene produced the paramagnetic [Ni(H2L)Cl]Cl complex. The crystal structure of this complex was established by X-ray diffraction.
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References
A. von Zelewsky and O. Mamula, J. Chem. Soc., Dalton Trans., 2000, 219.
O. Mamula and A. von Zelewsky, Coord. Chem. Revs, 2003, 242, 87.
A. V. Tkachev, Ross. Khim. Zh., 1998, 42, 42 [Mendeleev Chem. J., 1998, 42 (Engl. Transl)].
S. V. Larionov and A. V. Tkachev, Ross. Khim. Zh., 2004, 48, 154 [Mendeleev Chem. J., 2004, 48 (Engl. Transl.)].
S. V. Larionov, L. I. Myachina, R. F. Klevtsova, L. A. Glinskaya, L. A. Sheludyakova, S. N. Bizyaev, and A. V. Tkachev, Dokl. Akad. Nauk, 2004, 397, 214 [Dokl. Chem., 2004, 397, 156 (Engl. Transl.)].
S. V. Larionov, L. I. Myachina, R. F. Klevtsova, L. A. Glinskaya, L. A. Sheludyakova, S. N. Bizyaev, and A. V. Tkachev, Zh. Neorg. Khim., 2005, 50, 582 [Russ. J. Inorg. Chem., 2005, 50, 521 (Engl. Transl.)].
R. F. Klevtsova, L. A. Glinskaya, L. I. Myachina, and S. V. Larionov, Zh. Strukt. Khim., 2005, 46, 1141 [Russ. J. Struct. Chem., 2005, 46, 1104 (Engl. Transl.)].
S. V. Larionov, L. I. Myachina, L. A. Sheludyakova, E. G. Boguslavskii, S. N. Bizyaev, and A. V. Tkachev, Zh. Neorg. Khim., 2007, 52, 112 [Russ. J. Inorg. Chem., 2007, 52, 42 (Engl. Transl.)].
S. V. Larionov, A. V. Tkachev, L. I. Myachina, S. N. Bizyaev, L. A. Glinskaya, and R. F. Klevtsova, Dokl. Akad. Nauk, 2006, 411, 198 [Dokl. Chem., 2006, 411, 206 (Engl. Transl.)].
A. P. Petukhov, S. N. Bizyaev, and A. V. Tkachev, Izv. Akad. Nauk, Ser. Khim., 2001, 2013 [Russ. Chem. Bull., Int. Ed., 2001, 50, 2106].
G. M. Sheldrick, SHELXS97 and SHELXL97. Programs for the Refinement of Crystal Structures. Göttingen University, Göttingen, Germany, 1997.
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Dedicated to Academician G. A. Abakumov on the occasion of his 70th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1708–1711, September, 2007.
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Larionov, S.V., Myachina, L.I., Glinskaya, L.A. et al. Synthesis and structure of the [Ni(H2L)Cl]Cl complex with the chiral pentadentate nitrogen-containing ligand H2L derived from the natural terpenoid (+)-3-carene. Russ Chem Bull 56, 1771–1774 (2007). https://doi.org/10.1007/s11172-007-0275-x
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DOI: https://doi.org/10.1007/s11172-007-0275-x