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Synthesis and structure of 2,4-dinitrophenylcyanoacetamide derivatives as CH acids and their organic salts

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Abstract

C-Arylation of cyanoacetamides with chloro-2,4-dinitrobenzene was performed in acetonitrile in presence of potassium carbonate. The CH acids obtained react with triethylamine or N-methylmorpholine to give salts that contain anions possessing highly conjugated system of unsaturated bonds.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    Yu. G. Gololobov, I. R. Gol’ding, P. V. Petrovskii, K. A. Lyssenko & I. A. Garbuzova

  2. Institut Lavoisier-Franklin, Université de Versailles, 45 Avenue des Etats-Unis, 78035, Versailles Cedex, France

    F. Terrie

Authors
  1. Yu. G. Gololobov
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  2. I. R. Gol’ding
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  3. F. Terrie
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  4. P. V. Petrovskii
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  5. K. A. Lyssenko
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  6. I. A. Garbuzova
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Corresponding author

Correspondence to Yu. G. Gololobov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2365–2370, December, 2009.

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Gololobov, Y.G., Gol’ding, I.R., Terrie, F. et al. Synthesis and structure of 2,4-dinitrophenylcyanoacetamide derivatives as CH acids and their organic salts. Russ Chem Bull 58, 2443–2448 (2009). https://doi.org/10.1007/s11172-009-0342-6

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  • DOI: https://doi.org/10.1007/s11172-009-0342-6

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