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Structures and magnetic properties of new trinuclear CoII, NiII, and CuII complexes with trimethylacetate and 1,1-cyclohexanediacetate

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Abstract

The reactions of transition metal trimethylacetates [Cu2(Piv)4(HPiv)2], [Ni9(OH)6(Piv)12(HPiv)4], [Co(Piv)2] n (Piv− = −O2CBut) with 1,1-cyclohexanediacetic acid (H2Chda) neutralized by tetrabutylammonium hydroxide in the presence of 2,2-bipyridine (2,2′-bpy) afford linear trinuclear homometallic complexes [(2,2′-bpy)2Cu3(Chda)2(Piv)2]··2EtOH (1) and [(2,2′-bpy)2M3(Chda)2(Piv)2(EtOH)2] (M = NiII (2) or CoII (3)). In molecules of these compounds, anions of both mono- and dicarboxylic acids act as bridges between the transition metal atoms. Compounds 1–3 were characterized by X-ray diffraction, and their magnetic properties were studied. Spin-spin ferromagnetic interactions dominate in complexes 1–3 with CuII (S = 1/2) (1) and CoII (S = 3/2) (3) ions.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    N. V. Gogoleva, E. N. Zorina-Tikhonova, N. N. Efimov, E. A. Ugolkova, M. A. Kiskin, G. G. Aleksandrov, V. V. Minin, A. A. Sidorov, V. M. Novotortsev & I. L. Eremenko

  2. International Tomography Centre, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    A. S. Bogomyakov

  3. L. V. Pisarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 prosp. Nauki, 03028, Kiev, Ukraine

    S. V. Kolotilov

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  1. N. V. Gogoleva
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  8. G. G. Aleksandrov
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Correspondence to N. V. Gogoleva.

Additional information

Dedicated to Academician of the Russian Academy of Sciences O. N. Chupakhin on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1301–1307, June, 2014.

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Gogoleva, N.V., Zorina-Tikhonova, E.N., Efimov, N.N. et al. Structures and magnetic properties of new trinuclear CoII, NiII, and CuII complexes with trimethylacetate and 1,1-cyclohexanediacetate. Russ Chem Bull 63, 1301–1307 (2014). https://doi.org/10.1007/s11172-014-0594-7

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  • DOI: https://doi.org/10.1007/s11172-014-0594-7

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