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Synthesis and characterization of endohedral metallofulleride K(18-crown-6)[Ho@C82(C 2v)]

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Abstract

Endohedral metallofulleride K(18-crown-6)[Ho@C82(C 2v)] was synthesized for the first time using a redox reaction of endohedral metallofullerene Ho@C82(C 2v) with the electron donor potassium perchlorotriphenylmethide K(18-crown-6)[C(C6Cl5)3]. The new salt was characterized by spectrophotometry and mass spectrometry.

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Authors and Affiliations

  1. Department of Fundamental Physics and Chemical Engineering, M. V. Lomonosov Moscow State University, Build. 51, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    V. M. Nekrasov

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. P. Bubnov, V. M. Martynenko & I. E. Kareev

  3. Barcelona Institute of Material Sciences, Campus UAB, 08193, Bellaterra, Spain

    E. Laukhina, J. Veciana & C. Rovira

  4. Research Center of Biomedicine, Bioingineering, Biomaterials, and Nanomedicine, C/Monforte de Lemos 3–5, Pabellуn 11, 28029, Madrid, Spain

    E. Laukhina

Authors
  1. V. M. Nekrasov
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  2. V. P. Bubnov
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  3. V. M. Martynenko
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  4. I. E. Kareev
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  5. E. Laukhina
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  6. J. Veciana
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  7. C. Rovira
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Corresponding author

Correspondence to I. E. Kareev.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2473–2476, October, 2015.

Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC), 08193 Bellaterra, Campus UAB, Spain

CIBER de Bioingenieria, Biomateriales y Nanomedicina (CIBER-BBN), C/Monforte de Lemos 3–5, Pabellon 11, 28029 Madrid, Spain

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Nekrasov, V.M., Bubnov, V.P., Martynenko, V.M. et al. Synthesis and characterization of endohedral metallofulleride K(18-crown-6)[Ho@C82(C 2v)]. Russ Chem Bull 64, 2473–2476 (2015). https://doi.org/10.1007/s11172-015-1179-9

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  • DOI: https://doi.org/10.1007/s11172-015-1179-9

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