Abstract
Silica gel with the additives of tetraalkylammonium halides serves as an efficient catalyst for the solvent-free insertion of carbon dioxide into epoxides (10–56 atm of CO2, 105–100 °C), leading to cyclic carbonates with quantitative conversion.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1866–1868, October, 2019.
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Lyubimov, S.E., Sokolovskaya, M.V., Chowdhury, B. et al. Silica gel modified with tetraalkylammonium halides as an available and efficient catalyst for the synthesis of cyclic organic carbonates from epoxides and CO2. Russ Chem Bull 68, 1866–1868 (2019). https://doi.org/10.1007/s11172-019-2637-6
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DOI: https://doi.org/10.1007/s11172-019-2637-6