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Hydroxy-containing ionic liquids as catalysts in the synthesis of organic carbonates from epoxides and CO2

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Abstract

Hydroxy-containing ionic liquids such as triethyl(3-hydroxypropyl)ammonium, 1-(3-hydroxypropyl)-3-methylimidazolium, 3-(2-hydroxyethyl)-1-methylimidazolium, and 1-(3-hydroxypropyl)pyridinium chlorides were used as catalysts for the addition of carbon dioxide to epoxides, which gives cyclic carbonates. The effect of CO2 pressure and reaction temperature on the conversion of epoxides, as well as a promoting effect of inorganic substrates were studied.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov, A. A. Zvinchuk & V. A. Davankov

  2. Indian Institute of Technology (Indian School of Mines), 826004, Dhanbad, India

    B. Chowdhury

Authors
  1. S. E. Lyubimov
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  2. A. A. Zvinchuk
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  3. B. Chowdhury
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  4. V. A. Davankov
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Corresponding author

Correspondence to S. E. Lyubimov.

Additional information

Dedicated to Academician of the Russian Academy of Sciences A. M. Muzafarov on the occasion of his 70th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1598–1600, August, 2020.

This work was financially supported by the Russian Science Foundation (Project No. 19-43-02031).

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Lyubimov, S.E., Zvinchuk, A.A., Chowdhury, B. et al. Hydroxy-containing ionic liquids as catalysts in the synthesis of organic carbonates from epoxides and CO2. Russ Chem Bull 69, 1598–1600 (2020). https://doi.org/10.1007/s11172-020-2941-1

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  • DOI: https://doi.org/10.1007/s11172-020-2941-1

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