Abstract
Phosphorylthioformic acid morpholides can be successfully used as a precursor in the synthesis of complexes of phosphoryl-substituted thiohydrazides with hydrazine and morpholine. The reaction of sterically hindered phosphorylthioformic acid morpholides with hydrazine hydrate proceeds chemoselectively with the formation of hydrazono(morpholino)methylphosphodiamides.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1604–1606, August, 2020.
This work was financially supported by the Russian Science Foundation (Project No. 18-73-00321).
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Kozlov, M.A., Volkova, Y.A. & Zavarzin, I.V. New transformations of phosphorylthioformic acid morpholides. Russ Chem Bull 69, 1604–1606 (2020). https://doi.org/10.1007/s11172-020-2943-z
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DOI: https://doi.org/10.1007/s11172-020-2943-z