Abstract
Entropies of formation (\(T\Delta_{f}S^{0})\) of aqueous fluorine containing anions were shown to follow different entropic patterns than those of oxygen or hydrogen containing anions. Approaches to estimation of the entropies of formation of these anions are based on “simple” entropic patterns, where simple means the use of parameters derived only from the stoichiometry of these species, which are investigated, discussed and commented upon.
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This article is dedicated to Professor Neil Bartlett, fellow fluorinophile and friend, on the occasion of his 75th birthday.
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Ponikvar, M., Jenkins, H.D.B. & Liebman, J.F. Patterns and estimation of the entropies of formation of fluorine containing aqueous anions. Struct Chem 18, 883–889 (2007). https://doi.org/10.1007/s11224-007-9189-3
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DOI: https://doi.org/10.1007/s11224-007-9189-3