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Syntheses, structures, and luminescent properties of two cadmium(II) and manganese(II) coordination polymers based on the 11-fluoro-dipyrido[3,2-a:2′,3′-c]-phenazine ligand

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Abstract

Two new coordination polymers, namely [Cd(4-nitro-1,2-BDC))(L)] (1) and [Mn(1,3-BDC)(L)] (2) (4-nitro-1,2-BDC = 4-nitro-1,2-benzenedicarboxylate, 1,3-BDC = 1,3-benzenedicarboxylate, and L = 11-fluoro-dipyrido[3,2-a:2′,3′-c]phenazine), have been synthesized from phen derivative L and dicarboxylates under hydrothermal conditions. Their crystal structures have been determined by single-crystal X-ray diffraction analyses and further characterized by physicochemical and spectroscopic methods. Both compounds 1 and 2 show 1D chain structures. However, neighboring chains of 2 are further joined together by π···π interactions. Furthermore, the compound 1 shows good fluorescence properties in solid state at room temperature.

Graphical Abstract

Two new coordination polymers based on 11-fluoro-dipyrido[3,2-a:2′,3′-c]phenazine and different dicarboxylates have been synthesized under hydrothermal conditions, where the fluorescence properties in solid state at room temperature have been studied.

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Acknowledgments

This work was supported by Jilin Province Science and Technology Development projects (No. 201105085) and the Ministry of Higher Education of Malaysia (Grant No. UM.C/HIR/MOHE/SC/12).

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Authors and Affiliations

  1. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Ministry of Education, College of Chemistry, Jilin Normal University, Siping, 136000, People’s Republic of China

    Zhi-Guo Kong, Xu-Ran Sun, Ling Li, Han-Xue Wang & Xiu-Yan Wang

  2. Department of Chemistry, University of Malaya, 50603, Kuala Lumpur, Malaysia

    Seik Weng Ng

  3. Chemistry Department, King Abdulaziz University, PO Box 80203, Jeddah, Saudi Arabia

    Seik Weng Ng

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  1. Zhi-Guo Kong
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  2. Xu-Ran Sun
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  3. Ling Li
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  4. Han-Xue Wang
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  5. Xiu-Yan Wang
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Correspondence to Xiu-Yan Wang.

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Kong, ZG., Sun, XR., Li, L. et al. Syntheses, structures, and luminescent properties of two cadmium(II) and manganese(II) coordination polymers based on the 11-fluoro-dipyrido[3,2-a:2′,3′-c]-phenazine ligand. Transition Met Chem 38, 449–453 (2013). https://doi.org/10.1007/s11243-013-9710-z

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  • DOI: https://doi.org/10.1007/s11243-013-9710-z

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