Abstract
The pore-size dependence of the acidic properties of mesoporous silica FSM-16 in the range from 1.8 to 3.8 nm was investigated with the catalysis of 2-butanol dehydration and using FTIR spectra of adsorbed pyridine. The activity was the highest for FSM-16 with a minimum pore diameter, and decreased with increasing pore size. Differences in the acid amounts of siliceous FSM-16 and the strength dependent on the pore diameter were not confirmed by FTIR characterization using pyridine as a probe molecule.
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Acknowledgment
High purity water glass was supplied from Fuji Silysia Chem. Co. Ltd. The elemental analysis by X-ray fluorescence spectrometry was carried out by Professor M. Takaoka (Kyoto University).
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Yamamoto, T., Mori, S., Shishido, T. et al. Pore-Size Dependence of the Acidic Property of Mesoporous Silica FSM-16. Top Catal 52, 657–663 (2009). https://doi.org/10.1007/s11244-009-9217-1
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DOI: https://doi.org/10.1007/s11244-009-9217-1