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Experimental Investigation of the Ni-V-Zn Ternary System

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Abstract

The 450 and 600 °C isothermal sections of the Ni-V-Zn ternary system have been investigated through Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) and x-ray Diffraction (XRD) technique. Eight three-phase regions have been confirmed at the 450 °C section and nine three-phase regions exist at the 600 °C one. Experimental results indicate that it is difficult for Ni to dissolve in VZn3 and V4Zn5. The solid solubilities of V in γ(Ni2Zn11) and β1(NiZn) are 1.4 and 3.7 at.% at 450 °C, respectively, while V in γ and β1 are 2.5 and 4.0 at.% at 600 °C, respectively. The solid solubilities of Zn in Ni2V7, σ(Ni2V3), Ni2V and Ni3V are 0.5, 4.7, 2.3 and 2.6 at.% at 450 °C as well as 0.5, 9.5, 2.2 and 2.8 at.% at 600 °C, respectively. No ternary compound has been found in this work.

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References

  1. Sandelin, W. R. Galvanizing Characteristics of Different Types of Steel. American Hot Dip Galvanizers Association, (1940) 655-676

  2. J. Foct, P. Perrot, and G. Reumont, Interpretation of the Role of Silicon on the Galvanizing Reaction Based on Kinetics, Morphology and Thermodynamics, Scripta Meta., 1993, 28(10), p 1195-1200

    Article  Google Scholar 

  3. H. Guttman and P. Niessen, Reactivity of Silicon Steels Hot-Dip Galvanizing, J. Can. Metall. Q., 2013, 11(4), p 609-615

    Article  Google Scholar 

  4. G. Reumont, P. Perrot, and J. Foct, Thermodynamic Study of the Galvanizing Process in a Zn-0.1%Ni Bath, J. Mat. Sci., 1998, 33(19), p 4759-4768

    Article  ADS  Google Scholar 

  5. R. Fratesi, N. Ruffini, M. Malavolta, and T. Bellezze, Contemporary Use of Ni and Bi in Hot-Dip Galvanizing, Surf. Coat. Technol., 2002, 157(1), p 34-39

    Article  Google Scholar 

  6. J. Mackowiak and N.R. Short, Metallurgy of Galvanized Coatings, Int. Mater. Rev., 2013, 24(1), p 1-19

    Article  Google Scholar 

  7. M. B. Ferrero, P. T. Royo. 2-1 Reduction of Coating Thickness Improving Corrosion Resistance of Hot Dip Zn-Ni-V (Ecozinc) Versus Conventional Hot Dip Galvanizing Coatings; proceedings of the APGGC, F, 2007.

  8. B. Ferrero, M. Sprang. Zinc alloys yielding anticorrosive coatings on ferrous materials. US, 2002.

  9. Q.Y. Xu and W. Zhou, Oxidation Behaviors of Hot-Dipped Zn-Ni-V Alloy Coating, J. South China Univ. Technol. Nat. Sci. Ed., 2010, 38(9), p 85-89

    MathSciNet  Google Scholar 

  10. Q.Y. Xu and W. Zhou, Microstructure and Corrosion Electrochemical Behavior of Hot-dipped Zn-Ni-V Coating, J. Mat. Eng., 2011, 2, p 92-96

    ADS  Google Scholar 

  11. J.F. Smith, O.N. Carlson, and P.G. Nash, The Ni-V (Nickel-Vanadium) System, Bulletin of Alloy Phase Diagrams, 1982, 3(3), p 342-348

    Article  Google Scholar 

  12. M. Hansen and K. Anderko, Constitution of Binary Alloys, 2nd ed., McGraw-Hill, New York, 1958

    Google Scholar 

  13. T.B. Massalski, Binary Alloy Phase Diagrams, ASM Int, Mater Park, 1990

    Google Scholar 

  14. P. Nash and Y.Y. Pan, The Ni-Zn (Nickel-Zinc) System, Alloy Phase Diagrams, 1987, 8, p 422-430

    Article  Google Scholar 

  15. P. Nash. Phase diagrams of binary nickel alloys. ASM Int., (1991) 394-394

  16. W. Piotrowski, The Structure of Zinc Alloys with Vanadium, Hutnik, 1965, 32, p 135-143

    Google Scholar 

  17. H. Okamoto. V-Zn (Vanadium-Zinc). J. Phase Equilib. Diff., (2011) 259-259

  18. K. Chang, Y. Du, W. Sun, H. Xu, and L.C. Zhou, Thermodynamic Assessment of the V-Zn System Supported by key Experiments and First-Principles Calculations, Calphad, 2010, 34(1), p 75-80

    Article  Google Scholar 

  19. C. Wu, X. Su, D. Liu, X. Wang, J. Wang, Z. Li, and H. Peng, The V-Zn Binary System: new Experimental Results and Thermodynamic Assessment, Calphad, 2011, 35(3), p 403-410

    Article  Google Scholar 

  20. A.A. Nayeb-Hashemi and J.B. Clark, The Mg-Ni (Magnesium-Nickel) System, Bull. Alloy Phase Diagr., 1985, 6(3), p 238-244

    Article  Google Scholar 

  21. A. Seybolt and H. Sumsion, Studies on Vanadium Oxides, J. Met., 1953, 5, p 292-299

    Google Scholar 

  22. N.W. Gregory, Standard x-Ray Diffraction Powder Patterns, J. Phys. Today, 1954, 7, p 22-22

    Google Scholar 

  23. M.G. Chasanov, R. Schablaske, and P.D. Hunt, Zine-Vanadium Phase Diagram, Trans. Metall. Soc. AIME, 1963, 227, p 485-488

    Google Scholar 

  24. P. Villars and L.D. Calvert, Pearson’s Handbook of Crystal-lographic Data for Intermetallic Phases, ASM, Metals Park, 1997

    Google Scholar 

  25. S. Lau, Y.A. Chang, and S. Kou, TheRmodynamics of the β’-NiZn Intermetallic Phase Exhibiting the CsCl-Structure, Metall. Trans., 1974, 5(9), p 1979-1986

    Article  Google Scholar 

  26. W.W. Liang, Y.A. Chang, and S. Lau, The Effect of Lattice Disorder on the Thermodynamic Properties of the F.C. tetragonal β1-NiZn Alloys, Acta Metall., 1973, 21(5), p 629-637

    Article  Google Scholar 

  27. L. Hammond and D. Wright, Structural Characterisation of Corrosion Inhibiting Zinc Nickel Electroplate by Rietveld Methods, Mater. Sci. Forum, 1993, 133–136, p 501-506

    Article  Google Scholar 

  28. X. Su, N.Y. Tang, and J.M. Toguri, 450 & #xB0;C Isothermal Section of the Fe-Zn-Si Ternary Phase Diagram, J. Can. Metall. Q., 2013, 40(3), p 377-384

    Article  Google Scholar 

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Acknowledgments

This investigation is supported by the National Natural Science Foundation of China (Grant No. 51971189).

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Authors and Affiliations

  1. Key Laboratory of Materials Design and Preparation Technology of Hunan Province, Xiangtan University, Xiangtan, Hunan, 411105, People’s Republic of China

    Dongyu Cui, Helong Yang, Zhaohui Long, Zhi Li & Fucheng Yin

  2. School of Materials Science and Engineering, Xiangtan University, Xiangtan, Hunan, 411105, People’s Republic of China

    Dongyu Cui, Helong Yang, Zhaohui Long, Zhi Li & Fucheng Yin

  3. Powder Metallurgy Research Institute, Central South University, Changsha, Hunan, 410083, People’s Republic of China

    Dongyu Cui

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Cui, D., Yang, H., Long, Z. et al. Experimental Investigation of the Ni-V-Zn Ternary System. J. Phase Equilib. Diffus. 42, 91–101 (2021). https://doi.org/10.1007/s11669-020-00861-x

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