Skip to main content
Log in

H2S oxidation by multi-wall carbon nanotubes decorated with tungsten sulfide

  • Environmental Engineering
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Tungsten sulfide catalysts decorated on single and multiwall carbon nanotubes (SWNTs & MWNTs) and activated carbon were synthesized, and XRD, ICP, SEM, TEM and ASAP analyses were employed to acquire the characteristics of each catalyst. Afterwards a gas flow containing 5,000 ppm of H2S was passed over the catalyst in gas hour space velocity (GHSV) of 5,000 h−1, temperature of 65 °C, steam volume percent of 20 and O2/H2S ratio equal to 2. The results revealed that the catalyst supported on MWNTs exhibited higher conversion amongst its counterparts. Then effects of GHSV, steam volume percent in the feed, catalyst loading and temperature were investigated on conversion of hydrogen sulfide to elemental sulfur for tungsten sulfide catalyst decorated on MWNTs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Gas Processors Suppliers Association, Engineering Data Book, Vol. 2, 12th Ed. (2004).

  2. R. N. Maddox, Gas and Liquid Sweetening, Campbell Petroleum Series, Oklahoma (1998).

    Google Scholar 

  3. H. Pahlavanzadeh and M. Farazar, Korean J. Chem. Eng., 26, 1112 (2009).

    Article  CAS  Google Scholar 

  4. R. Wang, Sep. Purif. Technol., 31, 111 (2003).

    Article  CAS  Google Scholar 

  5. S. Mikhail, T. Zaki and L. Khalil, Appl. Catal. A, 227, 265 (2002).

    Article  CAS  Google Scholar 

  6. H. H. Funks, D. Fraenkel and V. H. Houlding, US Patent, 96,049 A1 (2002).

  7. J. Graham and C. Yaun, US Patent, 6,858,192 B2 (2005).

  8. E. Laperdrix, A. Sahibeddine, G. Costentin, M. Bensitel and J. C. Lavalley, Appl. Catal. B, 27, 137 (2000).

    Article  CAS  Google Scholar 

  9. W. D. Monnery, K. A. Hawboldt, A. Pollock and W. Y. Svrcek, Chem. Eng. Sci., 55, 5141, (2000).

    Article  CAS  Google Scholar 

  10. J. S. Chung, S. C. Paik, H. S. Kim, D. S. Lee and I. S. Nam, Catal. Today, 35, 37 (1997).

    Article  CAS  Google Scholar 

  11. S. Mendioroz, V. Munoz, E. Alvarez and J.M. Palacios, Appl. Catal., A, 132, 111 (1995).

    Article  CAS  Google Scholar 

  12. D. Rolke, P. Cornel, R. Lell, K. Stetzer and G. Neuroth, US Patent, 5,256,384 (1993).

  13. J. R. Graham and J. Cheng, US Patent, 7,241,430 B2 (2007).

  14. B. Cao, S. Wang and Q. Yuan, Chem. Eng. J., 118, 133 (2006).

    Article  Google Scholar 

  15. R. Miller, US Patent, 3,672,125 (1972).

  16. S.W. Chun, J. Y. Jang, D.W. Park, H. C. Woo and J. S. Chung, Appl. Catal. B, 16, 235 (1998).

    Article  CAS  Google Scholar 

  17. S. J. Jung, M.H. Kim, J. K. Chung, M. J. Moon, J. S. Chung, D.W. Park and H. C. Woo, Stud. Surf. Sci. Catal., 146, 621 (2003).

    Article  CAS  Google Scholar 

  18. K.V. Bineesh, D. K. Kim, H. J. Cho and D.W. Park, J. Ind. Eng. Chem., 16, 593 (2010).

    Article  CAS  Google Scholar 

  19. E. Keller, S. Ramani, D. Allison, S. Lusk, N. Hatcher, L. Swinney, K. Kirkendall, G. Torres, P. Stewart and T. Pruitt, US Patent, 7,226,572 B1 (2007).

  20. A. Carlsson and V.G. J. Heeringen, US Patent, 0,047,201 A1 (2009).

  21. P. Nguyen, D. Edouard, J.M. Nhut, M. J. Ledoux, C. Pham and C. P. Huu, Appl. Catal. B, 76, 300 (2007).

    Article  CAS  Google Scholar 

  22. N. Keller, C. P. Huu and M. J. Ledoux, Appl. Catal. A, 217, 205 (2001).

    Article  CAS  Google Scholar 

  23. D. Nguyen and T. Bandosz, Micropor. Mesopor. Mater., 92, 47 (2006).

    Article  Google Scholar 

  24. J. Klein and K. D. Henning, Fuel, 63, 1064 (1984).

    Article  CAS  Google Scholar 

  25. S. Yasyerli, G. Dogulsen and T. Doguimur, Catal. Today, 117, 271 (2006).

    Article  CAS  Google Scholar 

  26. S. Bashkova, F. S. Baker, X. Wu, T.R. Armstrong and V. Schwartz, Carbon, 45, 1354 (2007).

    Article  CAS  Google Scholar 

  27. A. Bagreev and T. J. Bandoz, Carbon, 39, 2303 (2001).

    Article  CAS  Google Scholar 

  28. A. Primavera, A. Trovarelli and P. Andreussi, Appl. Catal. A, 173, 185 (1998).

    Article  CAS  Google Scholar 

  29. A. Adib, A. Bagreev and T. J. Bandosz, Environ. Sci. Technol., 34, 686 (2000).

    Article  CAS  Google Scholar 

  30. T. J. Bandosz, Carbon, 37, 483 (1999).

    Article  CAS  Google Scholar 

  31. T. J. Bandsosz, J. Colloid Interface Sci., 246, 1 (2002).

    Article  Google Scholar 

  32. H. Shang, C. Liu, Y. Xu, J. Qiu and F. Wei, J. Nat. Gas Chem., 15, 203 (2006).

    Article  CAS  Google Scholar 

  33. J.M. Nhut, C. P. Huu, N. Keller and M. J. Ledoux, Catal. Today, 92, 91 (2004).

    Article  Google Scholar 

  34. A. M. Rashidi, M.M. Akbarnejad, A. A. Khodadadi, Y. Mortazavi and A. Ahmadpour, Nanotechnol, 18, 315605 (2007).

    Article  Google Scholar 

  35. A. Mohamadalizadeh, J. Towfighi, A. M. Rashidi, A. Mohajeri amd M. M. Golkar, Ind. Eng. Chem. Res., 50, 8050 (2011).

    Article  CAS  Google Scholar 

  36. A. Mohamadalizadeh, J. Towfighi, A. M. Rashidi, M. Manteghian, A. Mohajeri and R. Arasteh, Korean J. Chem. Eng., 28, 1221 (2011).

    Article  CAS  Google Scholar 

  37. R. Habibi, A. Rashidi, J. Towfighi and A. Mohamadalizadeh, Appl. Surf. Sci., 257, 434 (2010).

    Article  CAS  Google Scholar 

  38. L. Guana, H. Lia, Z. Shi and Z. Gu, Solid State Commun., 141, 459 (2007).

    Article  Google Scholar 

  39. A. Mohamadalizadeh, J. Towfighi, A. M. Rashidi, A. Mohajeri, S. Sattari and M. Manteghian, US Patent, 168,018 A1 (2011).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ali Mohamadalizadeh.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mohamadalizadeh, A., Towfighi, J., Adinehnia, M. et al. H2S oxidation by multi-wall carbon nanotubes decorated with tungsten sulfide. Korean J. Chem. Eng. 30, 871–877 (2013). https://doi.org/10.1007/s11814-012-0190-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-012-0190-1

Key words

Navigation