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Mesostructured SBA-15-Pr-SO3H: An efficient solid acid catalyst for one-pot and solvent-free synthesis of 3,4-dihydro-2-pyridone derivatives

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Abstract

3,4-Dihydro-2-pyridone derivatives have been prepared efficiently via a one-pot four-component reaction of benzaldehyde derivatives, Meldrum’s acid, methyl acetoacetate and ammonium acetate in the presence of sulphonic acid-functionalized ordered nanoporous SBA-15 as a nano heterogeneous catalyst under solvent-free conditions. This process is a simple, environmentally friendly, rapid and high yielding reaction.

A one-pot facile methodology for the synthesis of a series of 3,4-dihydro-2-pyridone derivatives in the presence of catalytic amount of SBA-Pr-SO3H under solvent-free conditions was developed. High yields, simple work-up procedure, no side reactions and simplicity in process are the advantages of this method.

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Acknowledgement

We thank the Research Council of Alzahra University and the University of Tehran for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Alzahra University, Vanak Square, Tehran, 1993893973, Iran

    GHODSI MOHAMMADI ZIARANI & SOMAYEH MOUSAVI

  2. School of Chemistry, College of Science, University of Tehran, Tehran, Iran

    NEGAR LASHGARI & ALIREZA BADIEI

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  1. GHODSI MOHAMMADI ZIARANI
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  2. SOMAYEH MOUSAVI
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  3. NEGAR LASHGARI
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  4. ALIREZA BADIEI
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Correspondence to GHODSI MOHAMMADI ZIARANI.

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MOHAMMADI ZIARANI, G., MOUSAVI, S., LASHGARI, N. et al. Mesostructured SBA-15-Pr-SO3H: An efficient solid acid catalyst for one-pot and solvent-free synthesis of 3,4-dihydro-2-pyridone derivatives. J Chem Sci 125, 1359–1364 (2013). https://doi.org/10.1007/s12039-013-0511-x

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  • DOI: https://doi.org/10.1007/s12039-013-0511-x

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