Skip to main content
Log in

Comparative studies on the hot corrosion behavior of air plasma spray and high velocity oxygen fuel coated Co-based L605 superalloys in a gas turbine environment

  • Published:
International Journal of Minerals, Metallurgy and Materials Aims and scope Submit manuscript

Abstract

An improvement in the corrosion resistance of alloys at elevated temperature is a factor for their potential use in gas turbines. In this study, CoNiCrAlY has been coated on the L605 alloy using air plasma spray (APS) and high-velocity oxygen fuel (HVOF) coating techniques to enhance its corrosion resistance. Hot corrosion studies were conducted on uncoated and coated samples in a molten salt environment at 850°C under cyclic conditions. Thermogravimetric analysis was used to determine the corrosion kinetics. The samples were subjected to scanning electron microscopy, energy-dispersive spectroscopy, and X-ray diffraction for further investigation. In coated samples, the formation of Al2O3 and Cr2O3 in the coating acts as a diffusion barrier that could resists the inward movement of the corrosive species present in the molten salt. Coated samples showed very less spallation, lower weight gain, less porosity, and internal oxidation as compared to uncoated sample. HVOF-coated sample showed greater corrosion resistance and inferred that this is the best technique under these conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. Gell, J.W. Wang, R. Kumar, J. Roth, C. Jiang, and E.H. Jordan, Higher temperature thermal barrier coatings with the combined use of yttrium aluminum garnet and the solution precursor plasma spray process, J. Therm. Spray Technol., 27(2018), No. 4, p. 543.

    Article  CAS  Google Scholar 

  2. J. Stringer, High-temperature corrosion of superalloys, Mater. Sci. Technol., 3(1987), No. 7, p. 482.

    Article  CAS  Google Scholar 

  3. N.R. Muktinutalapati, A. Natarajan, and M. Arivarasu, Hot corrosion of superalloys in boilers for ultra-supercritical power plants, [in] S. Cevik, eds., Superalloys for Industry Applications, IntechOpen, Croatia, 2018, p. 29.

    Google Scholar 

  4. N. Jegadeeswaran, K. Udaya Bhat, and M.R. Ramesh, Improving hot corrosion resistance of cobalt based superalloy (Superco-605) using HVOF sprayed oxide alloy powder coating, Trans. Indian Inst. Met., 68(2015), No. Suppl. 2, p. s309.

    Article  Google Scholar 

  5. N. Jegadeeswaran, M.R. Ramesh, S. Prakrathi, and K. Udaya Bhat, Hot corrosion behaviour of HVOF sprayed stellite-6 coatings on gas turbine alloys, Trans. Indian Inst. Met., 67(2014), No. 1, p. 87.

    Article  CAS  Google Scholar 

  6. G.R. Heath, P. Heimgartner, G. Irons, R.D. Miller, and S. Gustafsson, An assessment of thermal spray coating technologies for high temperature corrosion protection, Mater. Sci. Forum, 251–254(1997), p. 809.

    Article  Google Scholar 

  7. M. Arivarasu, M. Venkatesh Kannan, K. Devendranath Ramkumar, and N. Arivazhagan, Hot-corrosion resistance of dissimilar AISI 4340 and AISI 304L weldments in the molten salt environment at 600°C, Corros. Eng. Sci. Technol., 52(2017), No. 2, p. 114.

    Article  CAS  Google Scholar 

  8. H. Singh, Gitanjaly, S. Singh, and S. Prakash, High temperature corrosion behaviour of some Fe-, Co- and Ni-base superalloys in the presence of Y2O3 as inhibitor, Appl. Surf. Sci., 255(2009), No. 15, p. 7062.

    Article  CAS  Google Scholar 

  9. J. Cizek and J. Matejicek, Medicine meets thermal spray technology: A review of patents, J. Therm. Spray Technol., 27(2018), No. 8, p. 1251.

    Article  Google Scholar 

  10. T. Hussain, T. Dudziak, N.J. Simms, and J.R. Nicholls, Fireside corrosion behavior of HVOF and plasma-sprayed coatings in advanced coal/biomass co-fired power plants, J. Therm. Spray Technol., 22(2013), No. 5, p. 797.

    Article  CAS  Google Scholar 

  11. N. Bala, H. Singh, S. Prakash, and J. Karthikeyan, Investigations on the behavior of HVOF and cold sprayed Ni-20Cr coating on T22 boiler steel in actual boiler environment, J. Therm. Spray Technol., 21(2012), No. 1, p. 144.

    Article  CAS  Google Scholar 

  12. J.C. Tan, L. Looney, and M.S.J. Hashmi, Component repair using HVOF thermal spraying, J. Mater. Process. Technol., 92–93(1999), p. 203.

    Article  Google Scholar 

  13. L.M. Sun, Thermal spray coatings on orthopedic devices: When and how the FDA reviews your coatings, J. Therm. Spray Technol., 27(2018), No. 8, p. 1280.

    Article  CAS  Google Scholar 

  14. A. Mangla, V. Chawla, and G. Singh, Comparative study of hot corrosion behavior of HVOF and plasma sprayed Ni20Cr coating on SA213(T22) boiler steel in Na2SO4-60%V2O5 environment, Int. J. Eng. Sci. Res. Technol., 6(2017), No. 10, p. 674.

    CAS  Google Scholar 

  15. H. Singh, B.S. Sidhu, D. Puri, and S. Prakash, Use of plasma spray technology for deposition of high temperature oxidation/corrosion resistant coatings—A review, Mater. Corros., 58(2007), No. 2, p. 92.

    Article  CAS  Google Scholar 

  16. V. Mannava, A.S. Rao, N. Paulose, M. Kamaraj, and R.S. Kottada, Hot corrosion studies on Ni-base superalloy at 650°C under marine-like environment conditions using three salt mixture (Na2SO4 + NaCl + NaVO3), Corros. Sci., 105(2016), p. 109.

    Article  CAS  Google Scholar 

  17. N.S. Patel, V. Pavlík, and M. Boča, High-temperature corrosion behavior of superalloys in molten salts—A review, Crit. Rev. Solid State Mater. Sci., 42(2017), No. 1, p. 83.

    Article  CAS  Google Scholar 

  18. K. Zhang, M.M. Liu, S.L. Liu, C. Sun, and F.H. Wang, Hot corrosion behaviour of a cobalt-base super-alloy K40S with and without NiCrAlYSi coating, Corros. Sci., 53(2011), No. 5, p. 1990.

    Article  CAS  Google Scholar 

  19. J.B. Yan, Y.M. Gao, L. Liang, Z.Z. Ye, Y.F. Li, W. Chen, and J.J. Zhang, Effect of yttrium on the cyclic oxidation behaviour of HP40 heat-resistant steel at 1373 K, Corros. Sci., 53(2011), No. 1, p. 329.

    Article  CAS  Google Scholar 

  20. P. Choquet and R. Mevrel, Microstructure of alumina scales formed on NiCoCrAl alloys with and without yttrium, Mater. Sci. Eng. A, 120–121(1989), Part 1, p. 153.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Moganraj Arivarasu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jithesh, K., Arivarasu, M. Comparative studies on the hot corrosion behavior of air plasma spray and high velocity oxygen fuel coated Co-based L605 superalloys in a gas turbine environment. Int J Miner Metall Mater 27, 649–659 (2020). https://doi.org/10.1007/s12613-019-1943-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12613-019-1943-1

Keywords

Navigation