Abstract
An increase in heavy metal pollution in the soils of Hassi Messaoud (Algeria) due to intense industrialization and urbanization has become a serious environmental problem. There are three large industrial complexes that have been established in the region of Hassi Messaoud for petroleum extraction field and refinery. The region hosts several industrial facilities which are the main sources for hazardous wastes. Surface soil samples from 58 sampling sites (systematically sampled; 1 × 1 km regular grid), including different functional areas in Hassi Messaoud, were collected and analyzed. The results showed that the average concentrations of Cu, Ni, Mn, Pb and Zn in soil of Hassi Messaoud were up to 13.17, 35.78, 121.21, 130.97 and 61.08 mg/kg, respectively. Ni concentrations were comparable to background values, while Cu, Mn, Pb and Zn concentrations were higher than their corresponding background values. Among the functional areas, the industrial regions displayed the highest metal concentrations, while the lowest concentrations occurred in rural soil. Principal component analysis coupled with cluster analysis showed that: (1) Pb and Zn had anthropogenic sources; and (2) Ni, Cu and Mn were associated with parent materials. Contaminations in soils were classified as geoaccumulation index and enrichment factor. Pollution index values of Cu, Ni, Mn, Pb and Zn varied in the range of 0.04–5.41, 0.46–2.49, 0.01–5.73, 0.62–152.9 and 0.09–53.01, with mean values of 1.32, 1.08, 1.26, 5.64 and 3.1, respectively. The integrated pollution index (IPI) of all the analyzed samples varied from 0.42 to 31.59, with a mean of 2.48, and more than 5.45 % of samples are extremely contaminated; 18.18 % are heavily contaminated; 60 % are moderately contaminated; and others are low contaminated. The spatial distribution of IPI showed that desert and rural areas displayed relatively lower heavy metal contamination in comparison with other areas.
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References
Al-Khashman OA (2004) Heavy metal distribution in dust, street dust and soils from the work place in Karak Industrial Estate, Jordan. Atmos Environ 38:6803–6812
Banerjee ADK (2003) Heavy metal levels and solid phase speciation in street dusts of Delhi, India. Environ Pollut 123:95–105
Blaser P, Zimmermann S, Luster J, Shotyk W (2000) Critical examination of trace element enrichments and depletions in soils: As, Cr, Cu, Ni, Pb, and Zn in Swiss forest soils. Sci Total Environ 249:257–280
Boudries R, Dizene R (2008) Potentialities of hydrogen production in Algeria. Int J Hydrog Energy 33:4476–4487
Burgos P, Madejón M, Pérez-de-Mora A, Cabrera F (2008) Horizontal and vertical variability of soil properties in a trace element contaminated area. Int J Appl Earth Obs 10:11–25
Cabrera F, Clemente L, Barrientos ED, López R, Murillo JM (1999) Heavy metal pollution of soils affected by the Guadiamar toxic flood. Sci Total Environ 242:117–129
Chen TB, Zheng YM, Lei M, Huang ZC, Wu HT, Chen H et al (2005) Assessment of heavy metal pollution in surface soils of urban parks in Beijing, China. Chemosphere 60:542–551
Chon H, Kim K, Kim J (1995) Metal contamination of soils and dusts in Seoul metropolitan city, Korea. Environ Geochem Health 17:139–146
Cicchella D, De Vivo B, Lima A, Albanese S, Fedele L (2008) Urban geochemical mapping in Campania region, Italy. Geochem Explor Environ Anal 8:19–29
Coskun M, Steinnes E, Frontasyeva MV, Sjobakk TE, Demkina S (2006) Heavy metal pollution of surface soil in the Thrace region, Turkey. Environ Monit Assess 119:545–556
De Kimpe CR, Morel JL (2000) Urban soil management: a growing concern. Soil Sci 165:31–40
De Miguel E, Jimenez de Grado M, Llamas JF, Martın-Dorado A, Mazadiego LF (1998) The overlooked contribution of compost application to the trace element load in the urban soil of Madrid (Spain). Sci Total Environ 215:113–122
De Miguel E, Llamas JF, ChacÓn E, Mazadiego LF (1999) Sources and pathways of trace elements in urban environments: a multi-elemental qualitative approach. Sci Total Environ 235:355–357
Ellis JB, Revitt DM (1982) Incidence of heavy metals in street surface sediments: solubility and grain size studies. Water Air Soil Pollut 17:87–100
Ghazi M, Quaranta G, Duplay J, Hadjamor R, Khodja M, Ait Amar H, Kessaissia Z (2011) Life-Cycle Impact Assessment of oil drilling mud system in Algerian arid area. J Resour Conserv Recycl 55:1222–1231
Gonzáles-Macías C, Schifter I, Lluch-Cota DB, Méndez-Rodríguez L, Hernández Vázquez S (2006) Distribution, enrichment and accumulation of heavy metals in coastal sediments of Salina Cruz Bay, Mexico. Environ Monit Assess 118:211–230
Guo GH, Lei M, Chen TB, Song B, Li XY (2008) Effect of road traffic on heavy metals in road dusts and roadside soils. Acta Sci Circumst 28:1937–1945
Hakanson L (1980) An ecological risk index for aquatic pollution control—a sediment ecological approach. Water Res 14:975–1001
Han YM, Du PX, Cao JJ, Posmentier ES (2006) Multivariate analysis of heavy metal contamination in urban dusts of Xi’an, Central China. Sci Total Environ 355:176–186
Hseu ZY (2004) Evaluating heavy metal contents in nine composts using four digestion methods. Bioresour Technol 95:53–59
Imperato M, Adamo P, Naimo D, Arienzo M, Stanzione D, Violante P (2003) Spatial distribution of heavy metals in urban soils of Naples city (Italy). Environ Pollut 124:247–256
Jiang DZ, Teng EJ, Liu YL (1996) The contribution of difference on the element background values in soils and the analysis of variance of single factor on soil groups. Environ Monit Assess 2:21–24
Krishna AK, Govil PK (2008) Assessment of heavy metal contamination in soils around Manali industrial area, Chennai, Southern India. Environ Geol 54:1465–1472
Lee CS, Li XD, Shi WZ, Cheung SC, Thornton I (2006) Metal contamination in urban, suburban, and country park soils of Hong Kong: a study based on GIS and multivariate statistics. Sci Total Environ 356:45–61
Li XD, Poon CS, Liu PS (2001) Heavy metal contamination of urban soils and street dusts in Hong Kong. Appl Geochem 16:1361–1368
Li XD, Lee SL, Wong SC, Shi WZ, Thornton I (2004) The study of metal contamination in urban soils of Hong Kong using a GIS-based approach. Environ Pollut 129:113–124
Li C, Lu FY, Zhang Y, Liu TW, Hou W (2008) Spatial distribution characteristics of heavy metals in street dust in Shenyang city. Ecol Environ 17:560–564
Loska K, Wiechula D, Korus I (2004) Metal contamination of farming soils affected by industry. Environ Int 30:159–165
Madrid L, Diaz-Barrientos E, Madrid F (2002) Distribution of heavy metal contents of urban soils in parks of Seville. Chemosphere 49:1301–1308
Manta D, Angelone M, Bellanca A, Neri R, Sprovieri M (2002) Heavy metals in urban soils: a case study from the city of Palermo (Sicily), Italy. Sci Total Environ 300:229–243
Martin JAR, Arias ML, Corbi JMG (2006) Heavy metals contents in agricultural topsoils in the Ebro basin (Spain): application of the multivariate geostatistical methods to study spatial variations. Environ Pollut 144:1001–1012
Micó C, Recatalá L, Peris M, Sánchez J (2006) Assessing heavy metal sources in agricultural soils of European Mediterranean area by multivariate analysis. Chemosphere 65:863–872
Miner DK (1993) Automotive hydraulic brake tube: the case for 90–10 copper–nickel tubing. Society of Automotive Engineers. SAE Papers, Report No SAE 931028
Morton-Bermea O, Hernández-Álvarez E, González-Hernández G, Romero F, Lozano R, Beramendi-Orosco LE (2009) Assessment of heavy metal pollution in urban topsoils from the metropolitan area of Mexico City. J Geochem Explor 101:218–224
Müller G (1969) Index of geo-accumulation in sediments of the Rhine River. GeoJournal 2:108–118
Nimmo JW (1998) New design radiators. Can Copp 139:8–9
Rodrigues S, Pereira ME, Sarabando L, Lopes L, Cachada A, Duarte A (2006) Spatial distribution of total Hg in urban soils from an Atlantic coastal city (Aveiro, Portugal). Sci Total Environ 368:40–46
Romic M, Romic D (2003) Heavy metals distribution in agricultural topsoils in urban area. Environ Geol 43:795–805
Rubio B, Nombela MA, Vilas F (2000) Geochemistry of major and trace elements in sediments of the Ria de Vigo (NW Spain): an assessment of metal pollution. Mar Pollut Bull 11:968–980
Saby N, Arrouays D, Boulonne L, Jolivet C, Pochot A (2006) Geostatistical assessment of Pb in soil around Paris, France. Sci Total Environ 367:212–221
Salonen V, Korkka-Niemi K (2007) Influence of parent sediments on the concentration of heavy metals in urban and suburban soils in Turku, Finland. Appl Geochem 22:906–918
Sekhar KC, Chary NS, Kamala CT, Vairamani M, Anjaneyulu Y, Balaram V, Sorlie JE (2006) Risk communications: around the world-environmental risk assessment studies of heavy metal contamination in the industrial area of Kattedan, India a case study. Hum Ecol Risk Assess 12:408–422
Shi GT, Chen ZL, Xu SY, Zhang J, Wang L, Bi CJ, Teng JY (2008) Potentially toxic metal contamination of urban soils and roadside dust in Shanghai, China. Environ Pollut 156:251–260
Sonatrach (2006) Rapport annual. http://www.sonatrach-dz.com
Sun Y, Zhou Q, Xie X, Liu R (2010) Spatial, sources and risk assessment of heavy metal contamination of urban soils in typical regions of Shenyang, China. J Hazard Mater 174:455–462
Sutherland RA (2000) Bed sediment associated trace metals in an urban stream, Oahu, Hawaii. Environ Geol 39:611–627
Taylor SR (1964) Abundance of chemical elements in the continental crust: a new table. Geochim Cosmochim Acta 28:1273–1285
Thornton V (1991) Metal contamination of soils in urban areas. In: Bullock P, Greory PJ (eds) Soils urban environ. Blackwell, Oxford, pp 47–75
Wang XS, Qin Y (2005) Correlation between magnetic susceptibility and heavy metals in urban topsoil: a case study from the city of Xuzhou, China. Environ Geol 49:10–18
Wang XS, Qin Y (2006) Spatial distribution of metals in urban topsoils of Xuzhou (China): controlling factors and environmental implications. Environ Geol 49:905–914
Wang XS, Qin Y (2007) Some characteristics of the distribution of heavy metals in urban topsoil of Xuzhou, China. Environ Geochem Health 29:11–19
Wei B, Yang L (2010) A review of heavy metal contaminations in urban soils, urban road dusts and agricultural soils from China. Microchem J 94:99–107
Wilcke W, Muller S, Kanchanakool N, Zech W (1998) Urban soil contamination in Bangkok: heavy metal and aluminium partitioning in topsoils. Geoderma 86:211–228
Xinghui X, Xi C, Ruimin L, Hong L (2011) Heavy metals in urban soils with various types of land use in Beijing, China. J Hazard Mater 186:2043–2050
Yaqin JI, Yinchang F, Jianhui WU, Tan Z, Zhipeng B, Chiqing D (2008) Using geoaccumulation index to study source profiles of soil dust in China. J Environ Sci 20:571–578
Yassaa N, Cecinato A (2005) Composition of torched crude oil organic particulate emitted by refinery and its similarity to atmospheric aerosol in the surrounding area. Chemosphere 60:1660–1666
Zhang CS (2006) Using multivariate analyses and GIS to identify pollutants and their spatial patterns in urban soils in Galway, Ireland. Environ Pollut 142:501–511
Zhang XY, Sui YY, Zhang XD, Meng K, Herbert SJ (2007) Spatial variability of nutrient properties in black soil of northeast China. Pedosphere 17:19–29
Zheng YM, Chen TB, He JZ (2008) Multivariate geostatistical analysis of heavy metals in topsoils from Beijing, China. J Soil Sediment 8:51–58
Zhu W, Bian B, Li L (2008) Heavy metal contamination of road-deposited sediments in a medium size city of China. Environ Monit Assess 147:171–181
Acknowledgments
The author thanks Pr Smail MEHENNAOU, Laboratory of LESPA, University of Batna, for the chemical analysis. Also thanks Mr. BOUKHALKHAL AA, Scientific and Technical Research Centre for Arid Areas (CRSTRA), for its training in multivariate analysis. Thank you finally at Mr. AMIRA Soufiane for assistance in the analytical procedure.
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Benhaddya, M.L., Hadjel, M. Spatial distribution and contamination assessment of heavy metals in surface soils of Hassi Messaoud, Algeria. Environ Earth Sci 71, 1473–1486 (2014). https://doi.org/10.1007/s12665-013-2552-3
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DOI: https://doi.org/10.1007/s12665-013-2552-3