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Synthesis, crystal structure, and electrochemical properties of Ni(II) and Cu(II) complexes with two unsymmetrical N2O2 Schiff base ligands

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Abstract

Nickel(II) and copper(II) complexes of two unsymmetrical tetradentate Schiff base ligands [Ni(Me-salabza)] (1), [Cu(Me-salabza)] (2) and [Ni(salabza)] (3), {H2salabza = N,N′-bis[(salicylidene)-2-aminobenzylamine] and H2Me-salabza = N,N′-bis[(methylsalicylidene)-2-aminobenzylamine]}, have been synthesized and characterized by elemental analysis and spectroscopic methods. The crystal structures of 2 and 3 complexes have been determined by single crystal X-ray diffraction. Both copper(II) and nickel(II) ions adopt a distorted square planar geometry in [Cu(Me-salabza)] and [Ni(salabza)] complexes. The cyclic voltammetric studies of these complexes in dichloromethane indicate the electronic effects of the methyl groups on redox potential.

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Scheme 1
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Acknowledgments

Partial support of this work by the Isfahan University of Technology Research Council is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Isfahan University of Technology, 84156-83111, Isfahan, Iran

    Soraia Meghdadi, Mehdi Amirnasr, Maryam Bagheri, Fatemeh Ahmadi Najafabadi & Fahimeh Ziaee

  2. Faculty of Chemistry, Vienna University of Technology, Getreidemarkt 9/164SC, 1060, Vienna, Austria

    Kurt Mereiter

  3. Laboratoire de Cristallographie, École Polytechnique Fédérale de Lausanne, Le Cubotron-521, Dorigny, 1015, Lausanne, Switzerland

    Kurt Joß Schenk

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  1. Soraia Meghdadi
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  2. Mehdi Amirnasr
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  4. Fatemeh Ahmadi Najafabadi
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Correspondence to Mehdi Amirnasr.

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13738_2013_365_MOESM1_ESM.docx

Supplementary material 1 Crystallographic data for 2 and 3 have been deposited with the Cambridge Crystallographic Data Centre as supplementary publications, CCDC reference numbers 876390 and 876389. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; Fax: (+44) 1223-336-033; or Email: deposit@ccdc.cam.ac.uk)

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Meghdadi, S., Amirnasr, M., Bagheri, M. et al. Synthesis, crystal structure, and electrochemical properties of Ni(II) and Cu(II) complexes with two unsymmetrical N2O2 Schiff base ligands. J IRAN CHEM SOC 11, 985–991 (2014). https://doi.org/10.1007/s13738-013-0365-7

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