Abstract
Surface modification of as-received lithium foils was carried out using acid-base reactions of the native surface films on lithium metal with HF. Two types of as-received lithium foils covered with different native films were used as samples for this surface modification. One was a lithium foil having a very thin native surface film and the other one had a thicker native surface film. The surface condition of the lithium metal was analysed by X-ray photoelectron spectroscopy before and after the surface modification using HF, and the coulombic efficiency was measured electrochemically. The thickness of the surface film on the modified lithium foils was related to the Li2O layer thickness in the native film on the as-received lithium foils. The modified lithium foil which had the thinner native surface film provided more uniform deposition of lithium and a higher coulombic efficiency during charge and discharge cycles when propylene carbonate electrolyte with 1.0 m LiPF6 was used as the electrolyte. These results show that the initial condition of the native surface film plays an important role in surface modification with HF.
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References
J.P. Gabano, in J.P. Gabano (ed.) Lithium Batteries, Academic Press, London, 1983, chapter 2.
V.R. Koch, J. Power Sources 6 (1981) 357.
I. Yoshimatsu, T. Harai and J. Yamaki, J. Electrochem. Soc. 135 (1988) 2422.
M. Arakawa, S. Tobishima, Y. Nemoto, M. Ichimura and J. Yamaki, J. Power Sources 43–44 (1993) 27–35.
R. Selim and P. Bro, J. Electrochem. Soc. 121 (1974) 1457.
E. Peled, J. Electrochem. Soc. 126 (1979) 2047.
D. Aurbach, M.L. Daroux, P.W. Faguy and E. Yeager, J. Elec-trochem. Soc. 134 (1987) 1611.
D. Aurbach and O. Chusid, J. Electrochem. Soc. 140 (1993) L1.
D. Aurbach, A. Zaban, A. Schechter, Y. Ein-Eli, E. Zinigrad and B. Markovsky, J. Electrochem. Soc. 142 (1995) 2873.
D. Aurbach and E. Granot, Electrochim. Acta 42 (1997) 697.
M. Odziemkowski, M. Krell and D.E. Irish, J. Electrochem. Soc. 139 (1992) 3052.
K. Wang, G.S. Chottiner and D.A. Scherson, J. Phys. Chem. 97 (1993) 11075.
K. Wang, P.N. Ross, Jr., F. Kong and F. McLarnon, J. Electro-chem. Soc. 143 (1996) 422.
S.P.S. Yen, D. Shen, R.P. Vasquez, F.J. Grunthaner and R.B. Somoano, J. Electrochem. Soc. 128 (1981) 1434.
K.R. Zavadil and N.R. Armstrong, Surfa. Sci. 230 (1990) 47.
K. Kanamura, H. Tamura and Z. Takehara, J. Electroanal. Chem. 333 (1992) 127.
K. Kanamura, S. Shiraishi, H. Tamura and Z. Takehara, J. Electrochem. Soc. 141 (1994) 2379.
K. Kanamura, H. Tamura, S. Shiraishi and Z. Takehara, J. Electroanal. Chem. 394 (1995) 49.
K. Kanamura, H. Tamura, S. Shiraishi and Z. Takehara, Electrochim. Acta 40 (1995) 913.
D. Aurbach, I. Weissman, A. Schechter and H. Cohen, Langmuir, 12 (1996) 3991.
K. Naoi, M. Mori and Y. Shinagawa, J. Electrochem. Soc. 143 (1996) 2517.
M. Ishikawa, S. Yoshitake, M. Morita and Y. Matsuda, J. Electro-chem. Soc. 141 (1994) L159.
N. Koura, S. Tamura and M. Yoshitake, Denki Kagaku, 63 (1995) 623.
D. Aurbach and Y. Cohen, J. Electrochem. Soc. 143 (1997) 3525.
Y. Geronov, F. Schwager and R.H. Muller, J. Electrochem. Soc. 129 (1982) 1422.
J.G. Thevenin and R.H. Muller, J. Electrochem. Soc. 134 (1987) 273.
D. Aurbach and A. Zaban, J. Electroanal. Chem. 348 (1993) 155.
M. Odziemkowski and D.E. Irish, J. Electrochem. Soc. 140 (1993) 1546.
D. Pletcher, J.F. Rohan and A.G. Ritchie, Electrochim. Acta 39 (1994) 2015.
D. Aurbach, Y. Gofer, M. Ben-Zion and P. Aped, J. Electroanal. Chem. 339 (1992) 451.
T. Osaka, T. Momma, T. Tajima and Y. Matsumoto, J. Electro-chem. Soc. 142 (1995) 1057.
K.M. Abraham, J.S. Foos and J.L. Goldman, J. Electrochem. Soc. 131 (1984) 2197.
M. Morita, S. Aoki and Y. Matsuda, Electrochim. Acta 37 (1992) 119.
H. Nakamura, C. Wang, E. Mitani, T. Fujita and M. Yoshio, J. Surf. Finish. Soc. Jpn. 46 (1995) 1187.
T. Hirai, I. Yoshimatsu and J. Yamaki, J. Electrochem. Soc. 141 (1994) 2300.
A.T. Ribes, P. Beaunier, P. Willmann and D. Lemordant, J. Power Sources 58 (1996) 189.
K. Kanamura, S. Shiraishi and Z. Takehara, J. Electrochem. Soc. 141 (1994) L108.
K. Kanamura, S. Shiraishi and Z. Takehara, J. Electrochem. Soc. 143 (1996) 2187.
S. Shiraishi, K. Kanamura and Z. Takehara, J. Appl Electrochem. 25 (1995) 584.
T. Fujieda, N. Yamamoto, K. Saito, T. Ishibashi, M. Honjo, S. Koike, N. Wakabayashi and S. Higuchi, J. Power Sources 52 (1994) 197.
T. Osaka, T. Momma, K. Nishimura and T. Tajima, J. Electro-chem. Soc. 140 (1993) 2745.
D. Fauteux and R. Koksbang, J. Applied. Electrochem. 23 (1993) 1.
K. Kanamura, S. Shiraishi, H. Takezawa and Z. Takehara, Chem. Mater. 9 (1997) 1797.
K. Kanamura, H. Takezawa, S. Shiraishi and Z. Takehara, J. Electrochem. Soc. 144 (1997) 1900.
D.W.A. Sharp, in M. Stacey, J.C. Tatlow and A.G. Sharpe (ed.), Advances in Fluorine Chemistry, vol. 1, Butterworths, London, 1960, p. 69.
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Shiraishi, S., Kanamura, K. & Takehara, ZI. Influence of initial surface condition of lithium metal anodes on surface modification with HF. Journal of Applied Electrochemistry 29, 867–879 (1999). https://doi.org/10.1023/A:1003565229172
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DOI: https://doi.org/10.1023/A:1003565229172