Skip to main content
SpringerLink
Log in

Synthesis, magnetic and spectral studies of iron(III) and cobalt(II,III) complexes of 4-formylantipyrine N(4)-substituted thiosemicarbazones

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

The synthesis and characterization of complexes of iron(III), cobalt(II) and cobalt(III) with 4-formylantipyrine N(4)-methyl-, N(4)-dimethyl-, and 3-piperidylthiosemicarbazones are reported. Elemental analyses, molar conductivities, magnetic measurements and spectral (i.r., electronic and e.s.r.) studies have been used to elucidate the nature of the metal complexes. The i.r. spectra show that the thiosemicarbazones behave as bidentate or tridentate ligands, either in the thione or thiolato form. Different stereochemistries are proposed for the various cobalt(II) complexes on the basis of spectral and magnetic studies.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. G. Graciunescu, Ann. R. Acad. Farm., 43, 265 (1977).

    Google Scholar 

  2. B. G. Meffin, R. L. Williams, T. F. Baschke and M. Rowland, J. Pharm. Sci., 66, 135 (1977).

    CAS  Google Scholar 

  3. A. Kandil and A. Hamid, J. Drug Res., 12, 27 (1980).

    CAS  Google Scholar 

  4. A. M. Farghaly and A. Hozza, Pharmazie, 35, 596 (1980).

    CAS  Google Scholar 

  5. M. M. Shoukry, A. Kh. Ghoneim, E. M. Shoukry and M. H. El-Nagdy, Synth. React. Inorg. Met.-Org. Chem., 2, 15 (1982).

    Google Scholar 

  6. D. X. West, S. B. Padhye and P. B. Sonawane, Struct. Bonding, 76, 1 (1991) and refs therein.

    CAS  Google Scholar 

  7. D. X. West and N. M. Kozub, Transition Met. Chem., 21, 52 (1996) and refs therein.

    CAS  Google Scholar 

  8. N. N. Orlova, V. A. Aksevova, D. A. Selidovkin, N. S. Bogdanova and G. N. Pershin, Russ. Pharm. Toxicol., 348 (1968).

  9. D. J. Bauer, L. S. Vincent, C. H. Kempe and A. W. Downe, Lancet, 2, 494 (1963).

    Article  CAS  Google Scholar 

  10. K. Butler, US Pat. No. 3382266, 7 May 1968.

  11. H. W. Gansman, C. I. Rhykerd and H. R. Hinderliter, Bot. Gaz., 114, 292 (1953).

    Article  Google Scholar 

  12. A. C. Sartorelli, K. C. Agarwal, A. S. Tsiftsoglou and A. E. Moore, in G. Weber (Ed.) Advances in Enzyme Regulation, Pergamon, New York, 1977, Vol. 15, p. 117.

    Google Scholar 

  13. P. Sonawane, A. Kumbhar, S. B. Padhye and R. J. Butcher, Transition Met. Chem., 19, 277 (1994).

    Article  CAS  Google Scholar 

  14. J. P. Scovill, Phosphorus, Sulfur Silicon, 60, 15 (1991).

    CAS  Google Scholar 

  15. A. K. El-Sawaf, D. X. West, F. A. El-Saied and R. M. El-Bahnasawy, Transition Met. Chem., 22, 360 (1997).

    Article  CAS  Google Scholar 

  16. G. A. Bain, D. X. West, J. Krecji, J. Valdés-Martínez, S. Hernández-Ortega and R. Toscano, Polyhedron, 16, 855 (1997).

    Article  CAS  Google Scholar 

  17. W. J. Geary, Coord. Chem. Rev., 7, 81 (1971).

    Article  CAS  Google Scholar 

  18. D. X. West, B. L. Mokijewski, H. Gebremedhin and T. J. Romack, Transition Met. Chem., 17, 384 (1992).

    Article  CAS  Google Scholar 

  19. P. Sousa, J. A. Garcia-Vasquez and J. R. Masaguer, Transition Met. Chem., 9, 318 (1984).

    Article  Google Scholar 

  20. S. K. Nag and D. S. Joarder, Can. J. Chem., 54, 2827 (1976); S. K. Sengupta, S. K. Sahni and R. N. Kapoor, Acta Chim. Acad. Sci. Hungary, 104, 89 (1980); R. Roy, M. Chaudhury, S. K. Mondal and K. Nag, J. Chem. Soc., Dalton Trans., 1681 (1984); A. Z. El-Sonbati, E. M. Mabrouk and H. E. Megahed, Transition Met. Chem., 16, 280 (1991).

    Article  CAS  Google Scholar 

  21. F. A. El-Saied, R. M. El-Bahnasawy, M. A. Azzem and A. K. El-Sawaf, Polyhedron, 13, 1781 (1994).

    Article  CAS  Google Scholar 

  22. G. M. Abou El-Reash, I. M. Kenawy, U. I. El-Ayaan and M. A. Khattab, Synth. React. Inorg. Met.-Org. Chem., 24, 813 (1994).

    CAS  Google Scholar 

  23. K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, Wiley Interscience, New York, 1965, p. 173.

    Google Scholar 

  24. D. X. West, A. C. Whyte, B. L. Mokijewski and S. A. Frank, Transition Met. Chem., 16, 596 (1991).

    Article  CAS  Google Scholar 

  25. M. K. M. Nair and P. K. Radhakrishnan, Synth. React. Inorg. Met.-Org. Chem., 26, 263 (1996).

    CAS  Google Scholar 

  26. E. Ainscough, A. M. Brodie and N. G. Larsen, Inorg. Chim. Acta, 60, 25 (1982); L. Soto, A. Sancho and J. Borras, Synth. React. Inorg. Met.-Org. Chem., 16, 595 (1986).

    Article  CAS  Google Scholar 

  27. H. Okawa, M. Nakimoto, T. Izumitani and S. Kida, Bull. Chem. Soc. J., 55, 2671 (1982).

    Article  CAS  Google Scholar 

  28. M. Suzuki, H. Kanatomi, H. Koyama and I. Murase, Bull. Chem. Soc. J., 53, 1961 (1980); D. Kovala-Demertzi, J. M. Tsangaris and N. Hadjiliadis, Transition Met. Chem., 8, 140 (1983); M. Suzuki, H. Kanatomi, Y. Demura and I. Murase, Bull. Chem. Soc. J., 57, 1003 (1984).

    Article  CAS  Google Scholar 

  29. M. Mikuriya, H. Okawa and S. Kida, Bull. Chem. Soc. J., 53, 3717 (1980).

    Article  CAS  Google Scholar 

  30. M. Madan, H. M. Puranam, K. Alok, K. Munesh and K. J. Narendra, Inorg. Chem., 28, 96 (1989).

    Article  Google Scholar 

  31. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 4th Edit, Wiley Interscience, New York, 1980, p. 761.

    Google Scholar 

  32. H. Singh, L. S. D. Yadar and S. B. S. Mishra, J. Inorg. Nucl. Chem., 43, 1701 (1981).

    Article  CAS  Google Scholar 

  33. D. X. West, P. M Ahrweiler, G. Ertem, J. P. Scovill, D. L. Klayman, J. S. Flippen-Anderson, R. Gilardi, C. George and L. K. Pannell, Transition Met. Chem., 10, 264 (1985)

    Article  CAS  Google Scholar 

  34. C. A. Reed, T. Mashiko, S. P. Bentley, M. E. Kastner, W. R. Scheidt, K. Spartalian and G. Lang, J. Am. Chem. Soc., 101, 2948 (1979).

    Article  CAS  Google Scholar 

  35. Y. Nishida, A. Sumita, K. Hayashida, H. Oshima, S. Kida and Y. Maeda, J. Coord. Chem., 9, 161 (1979); N. Matsumoto, K. Kimoto, K. Nishida, A. Ohyoshi and Y. Maeda, Chem. Lett., 479 (1984).

    CAS  Google Scholar 

  36. C. Maichle, A. Castineiras, R. Carballo, D. X. West, H. Gebremedhin, M. A. Lockwood, C. E. Ooms and T. J. Romack, Transition Met. Chem., 20, 228 (1995) and refs therein.

    Article  CAS  Google Scholar 

  37. C. L. Jain, P. L. Mundley and R. Bajaj, J. Indian. Chem. Soc., 69, 777 (1992).

    CAS  Google Scholar 

  38. K. Mukkanti, K. B. Pandeya and R. P. Singh, Synth. React. Inorg. Met.-Org. Chem., 16, 229 (1986); B. Singh and U. Srivastava, Synth. React. Inorg. Met.-Org. Chem., 19, 279 (1989).

    CAS  Google Scholar 

  39. R. Beckett and B. F. Hoskins, J. Chem. Soc., Chem. Commun., 909 (1967).

  40. A. B. P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1968, p. 341.

    Google Scholar 

  41. R. Morassi, I. Bertini and L. Sacconi, Coord. Chem. Rev., 11, 343 (1973).

    Article  CAS  Google Scholar 

  42. I. Tucker, R. P. Singh and P. S. Zacharias, Indian J. Chem., 18A, 60 (1979).

    CAS  Google Scholar 

  43. K. K. Chatterjee, Indian J. Chem., 11, 678 (1973).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Illinois State University, Normal, IL, 61790-4160, USA

    Ayman K. El-Sawaf & Douglas X. West

  2. Department of Chemistry, El-Menoufia University, Shebin El-Kom, Egypt

    Ramadan M. El-Bahnasawy & Fathy A. El-Saied

Authors
  1. Ayman K. El-Sawaf
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Douglas X. West
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ramadan M. El-Bahnasawy
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Fathy A. El-Saied
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

El-Sawaf, A.K., West, D.X., El-Bahnasawy, R.M. et al. Synthesis, magnetic and spectral studies of iron(III) and cobalt(II,III) complexes of 4-formylantipyrine N(4)-substituted thiosemicarbazones. Transition Metal Chemistry 23, 227–232 (1998). https://doi.org/10.1023/A:1015767624270

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1015767624270

Keywords

Search

Navigation