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Distribution of mercury in the atmosphere over Idrija, Slovenia

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Abstract

Idrija mine, the second largest mercury mine in the world, was in use since 1490. More than 107 000 tons of Hg were produced in its five centuries of history until 1990 when production was reduced to a few hundred kilos per year. The average recovery rate of mercury has been estimated to 73%; much of the remaining 27% was dissipated into the environment. In spite of present minimal levels of production, and only a few days of smelter operation per year, a real time survey with a mercury Zeeman analyser in a car showed relatively high mercury concentrations in the air. Amounts of 300--4000 ng Hg m-3 have been found around both the major sources of mercury vapour, the smelter and mine ventilation shaft -- while the amounts at the Old Place, at the City Museum, and near the Nikova-Idrijca confluence are of the order of 50 ng m-3. Polluted air will be transported from those sources to a degree which depends on the weather conditions, mainly the direction and intensity of the wind. The high mercury contents in the air are not only due to anthropogenic sources (smelter and the ventilation shaft, dumps and smelter slag used in construction), but may also partly be natural as in the Pront area, where the outcropping bedrock contains native mercury.

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References

  • Adriano, D.C. 1986. Trace Elements in the Terrestrial Environment. Springer-Verlag, New York, Berlin, Heidelberg, Tokyo.

    Google Scholar 

  • Byrne, A.R. and Kosta, L. 1970. Studies on the distribution and uptake of mercury in the area of mercury mine at Idrija, Slovenia. Vestnik Slovenskega kemijskega društva, 17, 5–11.

    Google Scholar 

  • Drovenik, M. 1990. Importance of Idrija mine for understanding of mineral deposits (in Slovenian). Idrijski razgledi, 34, 12–16.

    Google Scholar 

  • Förstner, U. and Wittmann, G.T.W. 1979. Metal Pollution in the Aquatic Environment. Springer-Verlag, Berlin, Heidelberg, New York.

    Google Scholar 

  • Gosar, M. 1992. Estimation of mercury concentrations in sediments of the Idrijca river (in Slovenian). In: Proceedings of 3rd Conference on Pollution and Environmental Protection, 21–23 September 1992, pp. 213–217. Zavod za tehnično izobraževanje, Ljubljana.

    Google Scholar 

  • Gosar, M., Pirc, S. and Bidovec, M. 1995. Mercury in the Idrijca river sediments as a reflection of mining and smelting activities of the mercury mine Idrija. In: Proceedings of the 10th International Conference on Heavy Metals in the Environment, Vol. 1, pp. 311–314. CEP, Edinburgh.

    Google Scholar 

  • Grašič, M. 1973. Development of method for determination of mercury in the air and standardization of the procedure (in Slovenian). Diploma thesis, University of Ljubljana.

  • Hess, A. 1991. Vorläufige Mitteilungen über Schwermetallbelastung der Böden in Umfeld der Quecksilberlagerstätte Idrija (Slowenien). Geologija, 33, 479–486.

    Google Scholar 

  • Hess, A. 1993. Verteilung, Mobilität und Verfügbarkeit von Hg in Böden und Sedimenten am Beispiel zweier hochbelasteter Industriestandorte. Heidelberger Geowissenschaftliche Abhandlungen, Heidelberg.

    Google Scholar 

  • Kavčič, I. 1974. Degree of the of air pollution in Idrija (in Slovenian). Idrijski razgledi, 19, 25–29.

    Google Scholar 

  • Kavčič, J. 1991. 500 years of Idrija mine (in Slovenian). Idrijski razgledi, 35, 81–84.

    Google Scholar 

  • Kobal, A., Nanut, E., Stegnar, P., Zvonarič, T. and Horvat, M. 1991. Estimation of mercury in air and water in Idrija (1986) (in Slovenian). Idrijski razgledi, 36, 100–102.

    Google Scholar 

  • Kosta, L., Byrne, A.R., Zelenko, V., Stegnar, P., Dermelj, M. and Ravnik, V. 1974. Studies on the uptake, distribution and transformations of mercury in living organisms in the Idrija Region and comparative areas. Vestnik Slovenskega kemijskega društva, 21, 49–76.

    Google Scholar 

  • Lindqvist, O. and Rodhe, H. 1985. Atmospheric mercury — a review. Tellus, 37B, 136–159.

    Google Scholar 

  • Lupšina, V., Horvat, M., Jeran, Z. and Stegnar, P. 1992. Investigation of mercury speciation in lichens. Analyst, 117, 673–675.

    Google Scholar 

  • Lupšina-Miklavčič, V. 1994. Determination of low Hg concentrations in the air (in Slovenian). MSc thesis, University of Ljubljana.

  • Mashyanov, N.R. and Reshetov V.V. 1995. Geochemical ecological monitoring using remote sensing technique. Science of the Total Environment, 159, 169–175.

    Google Scholar 

  • Miko, S., Durn, G., Palinkaš, L.A., Mashyanov, N.R., Namjesnik, K. and Ilyin, Y.T. 1992. Distribution of mercury, and aerosols of lead and cadmium in the atmosphere of Zagreb. Rudarsko-metalurški zbornik, 39, 370–386.

    Google Scholar 

  • Palinkaš, L.A., Sholupov, S.E., Mashyanov, N.R., Durn, G. and Miko, S. 1990. Mercury in atmosphere over rural urban and industrial parts of Zagreb. Rudarsko geološko naftni zbornik, 2, 19–27.

    Google Scholar 

  • Pirc, S. 1990. Geochemistry of human environment and health (in Slovenian). In: Proceedings of Seminar Health with Nature, 7 June 1990, pp. 22–35. Faculty of Medicine and Biothechnical Faculty, Ljubljana.

    Google Scholar 

  • Pirc, S. 1991. Mercury in the atmosphere of Idrija and surroundings (in Slovenian). Idrijski razgledi, 35,1–2, 111–112.

    Google Scholar 

  • Scheffer, F. and Schachtschabel, P. 1989. Lehrbuch der Bodenkunde. Ferdinand Enke Verlag, Stuttgart.

    Google Scholar 

  • Slemr, R., Schuster, G. and Seiler, W. 1985. Distribution, speciation, and budget of atmospheric mercury. Journal of Atmospheric Chemistry, 3, 407–434.

    Google Scholar 

  • Sholupov, S.E., Drevalj. T.V., Mashyanov, N.R. and Platonova, N.R. 1988. O sposobkah graduirovki rtutnih gazoanalizatorov. Vestnik Leningradskogo universiteta, 7/14, 3–7.

    Google Scholar 

  • Soldano, B.A., Bien, P. and Kwan, P. 1975. Air-borne organo-mercury and elemental mercury emission with emphasis on central sewage facilities. Atmospheric Environment, 9, 941–944.

    Google Scholar 

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Gosar, M., Pirc, S., Ŝajn, R. et al. Distribution of mercury in the atmosphere over Idrija, Slovenia. Environmental Geochemistry and Health 19, 101–112 (1997). https://doi.org/10.1023/A:1018402605831

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