Abstract
Hydrotalcite-like compounds with boron anions in the interlayer were obtained using a coprecipitation method. The effect of different pH values during the preparation was investigated and the effect on crystallinity and phase distribution studied. The influence of different methods of acidity regulation was also analyzed. The efficiency of synthesis of boron-containing anionic clays was evaluated, and the good thermal stability of the materials was noted. Surface characteristics were determined by X-ray photoelectron spectroscopy and correlated to the bulk properties obtained by X-ray diffraction and 27Al and 11B MAS NMR. The samples tested in gas-phase Beckmann rearrangement showed caprolactam formation, and the results were related to the surface features.
Similar content being viewed by others
References
G. Dahlhoff, J.P.M. Niederer and W.F. Hölderich, Catal. Rev. Sci. Eng. 43(4) (2001) 335.
A. Corma and H. Garcia, Catal. Today 38 (1997) 257.
W.F. Hoelderich, Zeolites as Catalysts, Sorbents and Detergents Builders, in: Studies in Surface Science and Catalysis, Vol. 46 (1989) p. 193.
G. Dahlhoff, G.P. Heitmann, J.P.M. Niederer and W.F. Hölderich, J. Catal. 12 (1999) 186.
T. Curtin and B.K. Hodnett, Heter. Cat. and Fine Chem. III, in: Studies in Surface Science and Catalysis, Vol. 78, eds. M. Guisnet and J. Barbier (Elsevier, Amsterdam, 1993) p. 535.
G. Heitmann, G. Dahlhoff, J.P. Niederer and W.F. Hölderich, J. Catal. 194 (2000) 122.
H. Hichihashi and M. Kitamura, Catal. Today 2617 (2002) 1.
T. Curtin, J.B. McMonagle and B.K. Hodnett, Fine Chem. II, in: Studies in Surface Science and Catalysis, Vol. 59, eds. M. Guisnet and J. Barrault (Elsevier, Amsterdam, 1991) p. 531.
T. Curtin, J.B. McMonagle and B.K. Hodnett, Appl. Catal. A: General 93 (1992) 75.
W.F. Hölderich, J. Röseler, G. Heitman and A.T. Liebens, Catal. Today 37 (1997) 353.
J. Röseler, G. Heitman and W.F. Hölderich, Appl. Catal A: General 144 (1996) 319.
S. Sato, S. Hasabe, H. Sakurai, K. Urabe and Y. Izumi, Appl. Catal. A: General 29 (1987) 107.
T. Curtin, J.B. McMonagle and B.K. Hodnett, Appl. Cat. A: General 93 (1992) 91.
S. Sato, H. Sakurai, K. Urabe and Y. Izumi, Chem. Lett. 3 (1985) 1783.
S. Sato, K. Urabe and Y. Izumi, J. Catal. 102 (1986) 99.
T. Curtin, J.B. McMonagle and B.K. Hodnett, J. Catal. 142 (1993) 172.
J.T. Lin and S. Cheng, J. Chin. Chem. Soc. 46 (1999) 779.
S. Cheng, J.T. Lin, in: Synth. Microporous Mater., Vol. 2, eds. M.L. Occelli and H. Robson (Van Nostrand Reinhold, New York, 1992) p. 170.
M.P. Kaminsky and A. Bhattacharyya, European Patent 0 536 879, 1993 Amoco Corporation.
A. Bhattacharyya and D.B. Hall, Inorg. Chem. 31 (1992) 3869.
Liansheng Li, Xinsheng Liu et al., Chem. Mater. 8 (1996) 204.
P. Albers, K. Seibold, T. Haas, G. Prescher and W.F. Hölderich, J. Catal. 176 (1998) 561.
F. Cavani, F. Trifirò and A. Vaccari, Catal. Today 11 (1991) 176.
T.R. Baldwin and R. Burch, Appl. Catal. 66 (1990) 359.
J. Röseler, G. Heitmann and W.F. Hölderich, Appl. Catal. 144 (1996) 319.
J.B. Farmer in: Adv. Inorg. Chem. Radiochem., Vol. 25 (Academic Press, 1982) p. 187.
M.A. Straninick, M. Houalla and D.M. Hercules, J. Catal. 104 (1987) 396.
H. Morishige and Y. Akai, Bull. Soc. Chim. Belg. 104(4–5) (1995) 253.
J.L. Dubois and S. Fujieda, Preparation of Catalysts VI, Scientific Bases for the Preparation of Heterogeneous Catalysts, in: Studies in Surface Science and Catalysis, Vol. 91, ed. G. Poncelet (Elsevier, Amsterdam, 1995) p. 833.
F.M. Bautista, J.M. Campelo, A. Garcia, D. Luna, J.M. Marinas, M.C. Moreno, A.A. Romero, J.A. Navio and M. Macias, J. Catal. 173 (1998) 435.
F. Dumeignil, M. Guelton, M. Rigole, J.P. Amoureux, C. Fernandez and J. Grimblot, Coll. Surf. A Phys. 158 (1999) 75.
G. Engelhardt and D. Michel, High Resolution Solid State NMR of Silicates and Zeolites (Wiley, New York, 1987).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bechara, R., D'Huysser, A., Fournier, M. et al. Synthesis and Characterization of Boron Hydrotalcite-Like Compounds as Catalyst for Gas-Phase Transposition of Cyclohexanone-Oxime. Catalysis Letters 82, 59–67 (2002). https://doi.org/10.1023/A:1020535923499
Issue Date:
DOI: https://doi.org/10.1023/A:1020535923499