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The Hot Corrosion of Fe-Mn-Al–C Alloy with NaCl/Na2SO4 Coating Mixtures at 750°C

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Abstract

The high-temperature corrosion behavior of Fe-30.1Mn-9.7Al-0.77C alloy initially coated with 2 mg/cm2 NaCl/Na2SO4 (100/0, 75/25, 50/50, 25/75 and 0/100 wt.%) deposits has been studied at 750°C in air. The result shows that weight-gain kinetics in simple oxidation reveals a steady-state parabolic rate law after 3 hr, while the kinetics with salt deposits all display multi-stage growth rates. The corrosion morphology of the alloy with 100% Na2SO4 coating is similar to that of simple oxidation. NaCl acts as the predominant corrosion species for Fe-Mn-Al-C alloy, inhibiting the formation of a protective oxide scale. For the alloy coated with over 50% NaCl in salts, NaCl induces selective oxidation of manganese and results in the formation of secondary ferrite in the alloy substrate as well as void-layers with different densities of voids layer by layer in the secondary-ferrite zone.

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Authors and Affiliations

  1. Department of Mechanical Engineering, National Taiwan University of Science and Technology, Taipei, Taiwan, R.O.C. E-mail

    C.-J. Wang, Y.-C. Chang & Y.-H. Su

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  1. C.-J. Wang
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  2. Y.-C. Chang
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  3. Y.-H. Su
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Wang, CJ., Chang, YC. & Su, YH. The Hot Corrosion of Fe-Mn-Al–C Alloy with NaCl/Na2SO4 Coating Mixtures at 750°C. Oxidation of Metals 59, 115–133 (2003). https://doi.org/10.1023/A:1023022100300

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