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Synthesis of peroxide compounds by the BF3-catalyzed reaction of acetals and enol ethers with H2O2

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Abstract

Aliphatic and alicyclic gem-bis-hydroperoxides and their derivatives, bis(1-hydroperoxycycloalkyl) and bis(1-hydroperoxyalkyl) peroxides, dispiro- and tetraalkyl-1,2,4,5-tetroxanes were synthesized by the reaction of aliphatic and alicyclic acetals and enol ethers with H2O2 in the presence of BF3 in anhydrous Et2O.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    A. O. Terent"ev, A. V. Kutkin, M. M. Platonov, Yu. N. Ogibin & G. I. Nikishin

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    I. I. Vorontsov & M. Yu. Antipin

Authors
  1. A. O. Terent"ev
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  2. A. V. Kutkin
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  3. M. M. Platonov
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  4. I. I. Vorontsov
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  5. M. Yu. Antipin
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  6. Yu. N. Ogibin
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  7. G. I. Nikishin
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Terent"ev, A.O., Kutkin, A.V., Platonov, M.M. et al. Synthesis of peroxide compounds by the BF3-catalyzed reaction of acetals and enol ethers with H2O2 . Russian Chemical Bulletin 53, 681–687 (2004). https://doi.org/10.1023/B:RUCB.0000035657.58776.cc

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  • DOI: https://doi.org/10.1023/B:RUCB.0000035657.58776.cc

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