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Instability of detonation waves in FEFO/methanol solutions

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Combustion, Explosion, and Shock Waves Aims and scope

Abstract

A VISAR interferometer and a high-speed streak camera are used to study the structure of detonation waves in bis-(2-fluoro-2,2-dinitroethyl)-formal (FEFO) mixtures with methanol, whose mass concentration varied in the range of 0–35%. It is shown that the two types of instability existing in liquid explosives, which are the one-dimensional instability of the detonation front and the reaction failure wave instability on the edge of the charge, can be implemented in any combination. The reaction time of the studied mixtures is determined, and the different character of the dependence of the critical diameter of detonation and the reaction time on the diluent concentration is demonstrated.

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References

  1. K. I. Shchelkin and Y. K. Troshin, Gasdynamics of Combustion (Izd. Akad. Nauk SSSR, Moscow, 1963; Mono Book, 1965).

    Google Scholar 

  2. B. V. Voitsekhovsky, V. V. Mitrofanov, and M. E. Topchiyan, The Structure of the Detonation Front in Gases (Izd. Sib. Otd. Akad. Nauk SSSR, Novosibirsk, 1963) [in Russian].

    Google Scholar 

  3. I. N. Zverev and N. N. Smirnov, Gas Dynamics of Combustion (Izd. Mosk. Univ., Moscow, 1987) [in Russian].

    MATH  Google Scholar 

  4. R. M. Zaidel’, “The Stability of Detonation Waves in Gas Mixtures,” Dokl. Akad. Nauk SSSR 136 (5), 1142–1145 (1961).

    Google Scholar 

  5. S. K. Aslanov, V. N. Budzirovskii, and K. I. Shchelkin, “The Study of the Gas Dynamic Stability of Detonation Wave of Arbitrary Profile,” Dokl. Akad. Nauk SSSR 182 (1), 53–55 (1968).

    Google Scholar 

  6. A. N. Dremin, S. D. Savrov, V. S. Trofimov, et al., Detonation Waves in Condensed Media (Nauka, Moscow, 1970) [in Russian].

    Google Scholar 

  7. Yu. B. Khariton, Detonability of Explosives. Questions of the Theory of Explosives (Izd. Akad. Nauk SSSR, Moscow, Leningrad, 1947), Vol. 1 [in Russian].

  8. Condensed Energy Systems: A Brief Encyclopedia, Ed. by B. P. Zhukov (Yanus-K, Moscow, 1999) [in Russian].

    Google Scholar 

  9. M. Finger, E. Lee, F. H. Helm, et al., “The Effect of Elemental Composition on the Detonation Behavior of Explosives,” in Proc. Sixth Symp. (Intern.) On Detonation, August 24–27, 1976, Coronado, California, USA (1976).

    Google Scholar 

  10. S. I. Torunov, A. V. Utkin, V. M. Mochalova, et al., “Steady-State Detonation Wave Parameters in a FEFO/Nitrobenzene Solution,” Fiz. Goreniya Vzryva 46 (5), 119–123 (2010) [Combust., Expl., Shock Waves 46 (5), 599–603 (2010)].

    Google Scholar 

  11. A. V. Utkin, V. M. Mochalova, S. I. Torunov, et al. “Instability of Detonation Waves in Nitromethane and FEFO,” Fiz. Goreniya Vzryva 51 (4), 87–93 (2015) [Combust., Expl., Shock Waves 51 (4), 476–481 (2015)].

    Google Scholar 

  12. I. M. Voskoboinikov, S. A. Dushenok, and A. A. Kotomin, “Critical Diameter of Detonation of Bisfluorodinitroethyl Formal Solutions,” Khim. Fiz. 17 (11), 130–139 (1998).

    Google Scholar 

  13. I. M. Voskoboinikov, S. A. Dushenok, and A. A. Kotomin, “The limits of the Shock-Wave Initiation of the Explosion of Liquid Bisfluorodinitroethyl Formal and 1.6-Diazide-2-Acetoxyhexane,” Khim. Fiz. 17 (12), 58–61 (1998).

    Google Scholar 

  14. L. L. Gibson, S. A. Sheffield, D. M. Dattelbaum, and D. B. Stahl, “Shock Initiation and Detonation Properties of Bisfluorodinitroethyl Formal (FEFO),” in Shock Compression of Condensed Matter-2011, Ed. by M. L. Elert, W. T. Buttler, J. P. Borg, et al. (Amer. Inst. of Physics, 2012), 978-0-7354-1006-0, pp. 323–326.

    Google Scholar 

  15. M. F. Gogulya et al., “Shock Wave Initiation of Liquid Explosives,” in Shock Compression of Condensed Matter-1999, Ed. by M. D. Furnish, L. C. Chhabildas, and R. S. Hixson (Amer. Inst. of Physics, 2000), 1-56396923-8/00, pp. 903–906.

    Google Scholar 

  16. V. M. Mochalova, A. V. Utkin, and A. V. Anan’in, “Effect of the Degree of Dispersion on the Detonation Wave Structure in Pressed TNETB,” Fiz. Goreniya Vzryva 43 (5), 90–95 (2007) [Combust., Expl., ShockWaves 43 (5), 575–579 (2007)].

    Google Scholar 

  17. A. V. Utkin, V. M. Mochalova, and S. I. Torunov, “Determining the Detonation Parameters of Liquid Explosives,” Khim. Fiz. 30 (6), 72–77 (2011).

    Google Scholar 

  18. V. M. Mochalova, A. V. Utkin, and S. M. Lapin, “Effect of Small Additions of Diethylenetriamine on the Width of the Reaction Zone in Detonation Waves in Nitromethane,” Fiz. Goreniya Vzryva 52 (3), 82–88 (2016) [Combust., Expl., Shock Waves 52 (3), 329–334 (2016)]

    Google Scholar 

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Correspondence to A. V. Utkin.

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Original Russian Text © A.V. Utkin, V.M. Mochalova, S.I. Torunov, S.A. Koldunov.

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Utkin, A.V., Mochalova, V.M., Torunov, S.I. et al. Instability of detonation waves in FEFO/methanol solutions. Combust Explos Shock Waves 53, 74–81 (2017). https://doi.org/10.1134/S0010508217010117

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