Abstract
The phase equilibrium in the AsSe-MnSe system has been studied using physicochemical characterization techniques (differential thermal analysis, X-ray diffraction, microstructural analysis, microhardness tests, and density measurements), and its phase diagram has been mapped out. The system is shown to be a pseudobinary join of the ternary system Mn-As-Se. At AsSe: MnSe = 1: 1, the system contains a compound of composition MnAsSe2, which melts incongruently at 750°C. The glass-forming region extends to 15 mol % MnSe. We have examined the crystallization behavior of the glasses. Solid AsSe dissolves up to 2 mol % MnSe, and solid MnSe dissolves up to 2.5 mol % AsSe.
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Original Russian Text © I.I. Aliev, T.M. Il’yasly, Sh.A. Gasangulieva, C.A. Veliyev, 2011, published in Neorganicheskie Materialy, 2011, Vol. 47, No. 7, pp. 787–790.
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Aliev, I.I., Il’yasly, T.M., Gasangulieva, S.A. et al. Phase equilibria and glass formation in the AsSe-MnSe system. Inorg Mater 47, 703–706 (2011). https://doi.org/10.1134/S0020168511070028
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DOI: https://doi.org/10.1134/S0020168511070028