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Composite mechanism of the catalytic hydrogenation of unsaturated hydrocarbons on hydrided magnesium intermetallides

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Abstract

Two temperature ranges are distinguished in the catalytic hydrogenation of unsaturated hydrocarbons on magnesium intermetallide hydrides. In the lower temperature range, the reaction proceeds by a composite mechanism, as is indicated by the fact that the rate of the catalytic hydrogenation of ethylene, n-butenes, and butadiene is equal to the rate of the reduction of these hydrocarbons with hydride hydrogen. It is assumed that, at higher temperatures, the reaction proceeds by a heterogeneous-homogeneous mechanism.

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References

  1. Boreskov, G.K., Geterogennyi kataliz (Heterogeneous Catalysis), Moscow: Nauka, 1986.

    Google Scholar 

  2. Buyanov, R.A. and Molchanov, V.V., Dokl. Akad. Nauk SSSR, 1990, vol. 315, no. 1, p. 124.

    CAS  Google Scholar 

  3. Ivanov, P.S., Novikova, A.V., Parenago, O.P., et al., Neftekhimiya, 1988, vol. 28, no. 3, p. 320.

    CAS  Google Scholar 

  4. Ivanov, P.S., Stytsenko, V.D., Eigel’son, I.A., et al., Neftekhimiya, 1989, vol. 29, no. 6, p. 762.

    CAS  Google Scholar 

  5. Prasad, K.H.V., Prasad, K.B.S., Mallikarjunan, M.M., and Vaidyeswaran, R., J. Catal., 1983, vol. 84, no. 1, p. 65.

    Article  CAS  Google Scholar 

  6. Goddard, S.A., Cortright, R.D., and Dumesic, J.A., J. Catal., 1992, vol. 137, no. 1, p. 186.

    Article  CAS  Google Scholar 

  7. Rekoske, J.E., Cortright, R.D., Goddard, S.A., et al., J. Phys. Chem., 1992, vol. 96, no. 4, p. 1880.

    Article  CAS  Google Scholar 

  8. Sobolev, V.I. and Panov, G.I., React. Kinet. Catal. Lett., 1985, vol. 29, no. 2, p. 443.

    Article  CAS  Google Scholar 

  9. Soga, K., Imamura, H., and Ikeda, S., J. Catal., 1979, vol. 56, no. 1, p. 119.

    Article  CAS  Google Scholar 

  10. Molchanov, V.V., Stepanov, A.A., Konstanchuk, I.G., Buyanov, R.A., Boldyrev, V.V., and Goidin, V.V., Dokl. Akad. Nauk SSSR, 1989, vol. 306, no. 2, p. 367.

    Google Scholar 

  11. Gorokhovatskii, Ya.B., Kornienko, T.P., and Shalya, V.V., Geterogenno-gomogennye reaktsii (Heterogeneous-Homogeneous Reactions), Kiev: Tekhnika, 1972.

    Google Scholar 

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    V. V. Molchanov, V. V. Goidin & R. A. Buyanov

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  1. V. V. Molchanov
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  2. V. V. Goidin
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  3. R. A. Buyanov
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Original Russian Text © V.V. Molchanov, V.V. Goidin, R.A. Buvanov, 2006, published in Kinetika i Kataliz. 2006, Vol. 47, No. 5, pp. 767–769.

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Molchanov, V.V., Goidin, V.V. & Buyanov, R.A. Composite mechanism of the catalytic hydrogenation of unsaturated hydrocarbons on hydrided magnesium intermetallides. Kinet Catal 47, 744–746 (2006). https://doi.org/10.1134/S0023158406050132

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  • DOI: https://doi.org/10.1134/S0023158406050132

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