Skip to main content
SpringerLink
Log in

Changes in the course of reaction and regeneration of a Pd-Ag/Al2O3 catalyst for the selective hydrogenation of acetylene

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The samples of Pd-Ag/Al2O3 catalysts for the selective hydrogenation of acetylene impurities in an ethane-ethylene mixture were studied using the IR spectroscopy of adsorbed CO, X-ray diffraction analysis, and thermogravimetry. In the course of reaction and regeneration, the total concentration of the supported metals (Pd and Ag) changed only slightly. The degree of accessibility of silver atoms to CO adsorption and the amount of these atoms in the nearest environment of palladium atoms decreased to result in an increase in the selectivity of acetylene hydrogenation to ethane. The decrease in the accessibility of silver was due to a change in the phase composition of the alumina support as a result of its rehydration. It was hypothesized that the resulting aluminum hydroxide with the boehmite morphology is a source of the strongest Lewis acid sites, which catalyze oligomerization processes on the catalyst surface.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Plate, N.A. and Slivinskii, E.V., Osnovy khimii i tekhnologii monomerov (Fundamentals of Monomer Chemistry and Engineering), Moscow: Nauka, 2002.

    Google Scholar 

  2. Khrenov, E.G., Perminova, E.A., Fal’kov, I.G., et al., Promyshlennost’ sinteticheskogo kauchuka (Synthetic Rubber Industry), Moscow: TsNIITENeftekhim, 1993, no. 2.

    Google Scholar 

  3. Bond, G.C., Appl. Catal., A, 1997, vol. 149, p. 3.

    Article  CAS  Google Scholar 

  4. Duca, D., Frusteri, F., Parmalina, A., et al., Appl. Catal., A, 1996, vol. 146, p. 269.

    Article  CAS  Google Scholar 

  5. Duca, D., Barone, G., Varga, Z., et al., Catal. Lett., 2001, vol. 72, nos. 1–2, p. 17.

    Article  CAS  Google Scholar 

  6. Shaikhutdinov, Sh.K., Frank, M., Baumer, M., et al., Catal. Lett., 2002, vol. 80, nos. 3–4, p. 115.

    Article  CAS  Google Scholar 

  7. Asplund, S., J. Catal., 1996, vol. 158, p. 267.

    Article  CAS  Google Scholar 

  8. Liu, R.-J., Crozier, P.A., Smith, C.M., et al., Appl. Catal., A, 2005, vol. 282, p. 111.

    Article  CAS  Google Scholar 

  9. Ostrovskii, N.M., Kinetika dezaktivatsii katalizatorov (Catalyst Deactivation Kinetics), Moscow: Nauka, 2001.

    Google Scholar 

  10. Voronova, G.A., Vodyankina, O.V., Belousova, V.N., et al., Kinet. Katal., 2003, vol. 44, no. 5, p. 713 [Kinet. Catal. (Engl. Transl.), vol. 44, no. 5, p. 652].

    Google Scholar 

  11. Paukshtis, E.A., Infrakrasnaya spektroskopiya v geterogennom kislotno-osnovnom katalize (Infrared Spectroscopy in Heterogeneous Acid-Base Catalysis), Novosibirsk: Nauka, 1992.

    Google Scholar 

  12. Huang, D.C., Chang, K.H., Pong, W.F., et al., Catal. Lett., 1998, vol. 53, p. 155.

    Article  CAS  Google Scholar 

  13. Muslehiddinoglu, J. and Vannice, M.A., J. Catal, 2003, vol. 213, p. 305.

    Article  CAS  Google Scholar 

  14. Giordano, L., Del Vitto, A., Pacchioni, G., et al., Surf. Sci., 2003, vol. 540, p. 63.

    Article  CAS  Google Scholar 

  15. Davydov, A.A., IK-spektroskopiya v khimii poverkhnosti okislov (IR Spectroscopy in Oxide Surface Chemistry), Novosibirsk: Nauka, 1984.

    Google Scholar 

  16. Temkin, O.N. and Bruk, L.G., Usp. Khim., 1983, vol. 52, no. 2, p. 206.

    CAS  Google Scholar 

  17. Akolekar, D.B. and Bhargava, S.K., J. Mol. Catal., 2000, vol. 157, p. 199.

    Article  CAS  Google Scholar 

  18. Alekseev, O.S. and Ryndin, Yu.A., Usp. Khim., 1992, vol. 61, no. 4, p. 765.

    CAS  Google Scholar 

  19. Mornar, A., Sarkany, A., and Varga, M., J. Mol. Catal. A: Chem., 2001, vol. 173, p. 185.

    Article  Google Scholar 

  20. Sarkany, A., React. Kinet. Catal. Lett., 2001, vol. 74, no. 2, p. 299.

    Article  CAS  Google Scholar 

  21. Prokudina, N.A., Chesnokov, V.V., Paukshtis, E.A., et al., Kinet. Katal., 1989, vol. 30, no. 4, p. 949.

    CAS  Google Scholar 

  22. Dzis’ko, V.A., Tarasova, D.V., and Karnaukhov, A.P., Fiziko-khimicheskie osnovy sinteza okisnykh katalizatorov (Physicochemical Foundations of the Synthesis of Oxide Catalysts), Novosibirsk: Nauka, 1978.

    Google Scholar 

  23. Paramzin, S.M., Zolotovskii, V.P., and Buyanov, R.A., Sib. Khim. Zh., 1992, no. 2, p. 130.

  24. Lamberov, A.A., Levin, O.V., Egorova, S.R., et al., Zh. Prikl. Khim., 2003, vol. 76, no. 1, p. 50.

    Google Scholar 

  25. Physical and Chemical Aspects of Adsorbents and Catalysts, Linsen, B.G., Ed., London: Academic, 1970.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kazan State University, Kazan, 420008, Tatarstan, Russia

    A. A. Lamberov, S. R. Egorova & I. R. Il’yasov

  2. OAO Nizhnekamskneftekhim, Nizhnekamsk, 423574, Tatarstan, Russia

    Kh. Kh. Gil’manov, S. V. Trifonov, V. M. Shatilov & A. Sh. Ziyatdinov

Authors
  1. A. A. Lamberov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. R. Egorova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. R. Il’yasov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Kh. Kh. Gil’manov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. V. Trifonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. M. Shatilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. Sh. Ziyatdinov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © A.A. Lamberov, S.R. Egorova, I.R. Il’yasov, Kh.Kh. Gil’manov, S.V. Trifonov, V.M. Shatilov, A.Sh. Ziyatdinov, 2007, published in Kinetika i Kataliz, 2007, Vol. 48, No. 1, pp. 143–149.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lamberov, A.A., Egorova, S.R., Il’yasov, I.R. et al. Changes in the course of reaction and regeneration of a Pd-Ag/Al2O3 catalyst for the selective hydrogenation of acetylene. Kinet Catal 48, 136–142 (2007). https://doi.org/10.1134/S0023158407010181

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158407010181

Keywords

Search

Navigation