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Catalytic conversions of dialkyl disulfides

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Abstract

The results of the studies of catalytic conversions of lower dialkyl disulfides performed at the Boreskov Institute of Catalysis (Siberian Branch, Russian Academy of Sciences) are summarized. The selective hydrogenolysis of dimethyl and diethyl disulfides with the formation of alkanethiols occurs in a hydrogen medium on transition metal sulfides. Dimethyl disulfide turns into dimethyl sulfide in an inert gas medium on oxide catalysts with acid and basic sites on their surface. Lower dialkyl disulfides are dehydrocyclized to thiophene under the action of sulfide catalysts. In an oxygen medium on the metal oxides and salts, diethyl disulfide and a lower disulfide concentrate are selectively oxidized to form alkanethiolsulfinates, alkanethiolsulfonates, and alkanesulfonic acids.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    A. V. Mashkina

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  1. A. V. Mashkina
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Correspondence to A. V. Mashkina.

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Original Russian Text © A.V. Mashkina, 2008, published in Kinetika i Kataliz, 2008, Vol. 49, No. 6, pp. 844–854.

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Mashkina, A.V. Catalytic conversions of dialkyl disulfides. Kinet Catal 49, 802–811 (2008). https://doi.org/10.1134/S0023158408060050

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