Abstract
The results of development of an industrial supported cobalt–silica gel catalyst for the Fischer–Tropsch synthesis are reported. The studies included the selection of a support and the determination of an optimum active component content, a calcination temperature, and the effect of doping with aluminum oxide on the physicochemical and catalytic properties of the Co–SiO2 system. The catalyst samples were characterized by a set of physicochemical methods. The on-stream stability of the supported cobalt–silica gel catalyst was tested in the continuous mode for 1000 h. In the course of the entire test cycle, the catalyst exhibited stable operation under varied synthesis temperature and gas space velocity, and it can be recommended for industrial applications. The experimental results were used for the preparation of a pilot batch of the catalyst.
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David, A., Wood, A., and Chikezie, N., J. Nat. Gas Sci. Eng., 2012, vol. 9, p. 196.
Khodakov, A.Y., Chu, W., and Fongarland, P., Chem. Rev., 2007, vol. 107, p. 1692.
Bekker, M., Louw, N.R., Rensburg, J.V., and Potgiete, J., Int. J. Cosmet. Sci., 2013, vol. 35, p. 99.
www.sasolwax.com/paraffin_wax.html. Accessed August 29, 2016.
Mordkovich, V.Z., Sineva, L.V., Kul’chakovskaya, E.V., and Asalieva, E.Yu., Katal. Prom–sti., 2015, no. 5, p. 23.
Ellepola, J., Thijssen, N., Grievink, J., Baak, G., Avhale, A., and Schijndel, J.V., Comput. Chem. Eng., 2012, vol. 42, p. 2.
Krylova, A.Yu. and Kozyukov, E.A., Solid Fuel Chem., 2007, vol. 41, no. 6, p. 335.
Grigor'ev, D.A., Neft’, Gaz Biznes, 2011, no. 3, p. 51.
Savost'yanov, A.P., Narochnyi, G.B., Yakovenko, R.E., Bakun, V.G., and Zemlyakov, N.D., Catal. Ind., 2014, vol. 6, no. 4, p. 292.
Yakovenko, R.E. and Narochnyi, G.B., Bakun V.G., Astakhov A.V., Izv. Vyssh. Uchebn. Zaved,. Severo-Kavkazskii Region, Tekh. Nauki, 2014, no. 6, p. 92.
Savost'yanov, A.P., Narochnyi, G.B., Yakovenko, R.E., Astakhov, A.V., Zemlyakov, N.D., Merkin, A.A., and Komarov, A.A., Catal. Ind., 2014, vol. 6, no. 3, p. 212.
Narochnyi, G.B., Yakovenko, R.E., Savost’yanov, A.P., and Bakun, V.G., Catal. Ind., 2016, vol. 8, no. 2, p. 139.
PDF-2, The Powder Diffraction File, International Center for Diffraction Data (ICCD), PDF-2 Release 2012. http://www.icdd.com.
The Rietveld Method, Young, R.A., Ed., Oxford: Oxford Univ. Press, 1995.
Satterfield, C., Heterogeneous Catalysis in Practice, New York: McGraw-Hill, 1980.
Boreskov, G.K., Geterogennyi kataliz (Heterogeneous Catalysis), Moscow: Nauka, 1986.
Krylov, O.V., Geterogennyi kataliz (Heterogeneous Catalysis), Moscow: Akademkniga, 2004.
Slivinskii, E.V., Kliger, G.A., Kuz’min, A.E., Abramova, A.V., and Kulikova, E.A., Ross. Khim. Zh., 2003, vol. 47, no. 6, p. 12.
Kibby, C., Catal. Today, 2013, vol. 215, p. 131.
Sun, J., Catal. Sci. Technol., 2014, vol. 4, p. 1260.
Yao, M., Catal. Sci. Technol., 2015, vol. 5, p. 2821.
Girardon, J.S., J. Catal., 2005, vol. 230, p. 339.
Chernavskii, P.A., Chu, Vei., Khodakov, A.Yu., Pankina, G.V., and Peskov, N.V., Russ. J. Phys. Chem. A, 2008, vol. 82, no. 6, p. 951.
Dzis'ko, V.A., Karnaukhov, A.P., and Tarasova, D.V., Fiziko-khimicheskie osnovy sinteza okisnykh katalizatorov (Physicochemical Foundations of the Synthesis of Oxide Catalysts), Novosibirsk: Nauka, 1978.
Kheifets, L.I. and Neimark, A.V., Mnogofaznye protsessy v poristykh sredakh (Multiphase Processes in Porous Media), Moscow: Khimiya, 1982.
Chu, W., Xu, J., Hong, J., Lin, T., and Khodakov, A., Catal. Today, 2015, vol. 256, p. 41.
Guo, P., Saw, W., Eyk, P., Ashman, P., Nathan, G., and Stechel, E., Energy Procedia, 2015, vol. 69, p. 1770.
Prieto, G., Concepción, P., Murciano, R., and Martínez, A., J. Catal., 2013, vol. 302, p. 37.
Tsubaki, N., Sun, S., and Fujimoto, K., J. Catal., 2001, vol. 199, p. 236.
Chu, W., Chernavskii, P.A., Gengembre, L., Pankina, G.A., Fongarland, P., and Khodakov, A.Y., J. Catal., 2007, vol. 252, p. 215.
Girardon, J.-S., Quinet, E., Griboval-Constant, A., Chernavskii, P.A., Gengembre, L., and Khodakov, A.Y., J. Catal., 2007, vol. 248, p. 143.
Beer, M., Kunene, A., Nabaho, D., Claeys, M., and Steen, E., J. South Afr. Inst. Min. Metall., 2014, vol. 114, no. 2, p. 157.
París, L., Lopez, J., Barrientos, F., and Pardo, M., in Catalysis, vol. 27, Spivey, J.J., Han, Y.-F., and Dooley, K.M., Eds., Cambridge: R. Soc. Chem., 2015, ch. 3, p. 62.
Jahangiri, H., Bennett, J., Mahjoubi, P., Wilson, K., and Gu, S., Catal. Sci. Technol., 2014, vol. 4, p. 2210.
Johnson, G.R. and Bell, A.T., ACS Catal., 2016, vol. 6, p. 100.
Zhang, Y., Nagamori, S., Hinchiranan, S., Vitidsant, T., and Tsubaki, N., Energy Fuels, 2006, vol. 20, p. 417.
Pei, Y., Ding, Y., Zhu, H., Zang, J., Song, X., Dongm, W., Wang, T., and Lu, Y., Catal. Lett., 2014, vol. 144, p. 1433.
Peng, X., Cheng, K., Kang, J., Gu, B., Yu, X., Zhang, Q., and Wang, Y., Angew. Chem., 2015, vol. 127, p. 4636.
Sedran, U.A. and Figoli, N.S., Appl. Catal., 1985, vol.19, p. 317.
Kruse, N., Machoke, A.G., Schwieger, W., and Guttel, R., ChemCatChem, 2015, vol. 7, p. 1018.
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Original Russian Text © A.P. Savost’yanov, R.E. Yakovenko, G.B. Narochnyi, V.G. Bakun, S.I. Sulima, E.S. Yakuba, S.A. Mitchenko, 2017, published in Kinetika i Kataliz, 2017, Vol. 58, No. 1, pp. 86–97.
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Savost’yanov, A.P., Yakovenko, R.E., Narochnyi, G.B. et al. Industrial catalyst for the selective Fischer–Tropsch synthesis of long-chain hydrocarbons. Kinet Catal 58, 81–91 (2017). https://doi.org/10.1134/S0023158417010062
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DOI: https://doi.org/10.1134/S0023158417010062