Abstract
The results of a study of the synthesis of products from CO and H2 on a supported industrial Co–Al2O3/SiO2 catalyst under medium and high pressures in the gas circulation mode are presented. It was found that an increase in pressure from 2.0 to 8.0 MPa led to an increase in the amount of formed alcohols and synthesis olefins by factors of 10.5 and 2.0, respectively. It was determined that alcohols obtained in the synthesis were not the products of olefin hydration. The effect of an increase in selectivity for C5+ products with temperature at a high pressure in the gas recirculation mode, which is atypical for the Fischer–Tropsch synthesis, was confirmed.
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REFERENCES
Dry, M.E., Catal. Today, 2002, vol. 71, p. 227.
Storch, H., Golumbic, N., and Anderson, R., The Fischer–Tropsch and Related Syntheses. Including a Summary of Theoretical and Applied Contact Catalysis, New York: Wiley, 1951.
Kungurova, O.A., Shtertser, N.V., Chermashentseva, G.K., Simentsova, I.I., and Khasin, A.A., Catal. Ind., 2017, vol. 9, no. 1, p. 23.
Golub’, F.S., Bolotov, V.A., and Parmon, V.N., Catal. Ind., 2020, vol. 13, no. 6, p. 168.
Khodakov, A.Y., Chu, W., and Fongarland, P., Chem. Rev., 2007, vol. 107, p. 1692.
Davis, B.H., Ind. Eng. Chem. Res., 2007, vol. 46, p. 8938.
Gao, X., Zhang, J., Chen, N., Ma, Q., Fan, S., Zhao, T., and Tsubaki, N., Chin. J. Catal., 2016, vol. 37, p. 510.
Guo, X., Guo, L., Cui, Y., Vitidsant, T., Reubroycharoen, P., Liu, G., Wu, J., Yoneyama, Y., Yang, G., and Tsubaki, N., Catal. Today, 2021, vol. 375, p. 290.
Abdelsayed, V., Shekhawat, D., Poston, J.A., and Spivey, J.J., Catal. Today, 2013, vol., 207, p. 65.
Zaman, S.F., Pasupulety, N., Al-Zahrani, A.A., Daous, M.A., Al-Shahrani, S.S., Driss, H., Petrov, L.A., and Smith, K.J., Appl. Catal., A, 2017, vol. 532, p. 133.
Heracleous, E., Liakakou, E.T., Lappas, A.A., and Lemonidou, A.A., Appl. Catal., A, 2013, vol. 455, p. 145.
Pei, Y., Liu, J., Zhao, Y., Ding, Y., Liu, T., Dong, W., Zhu, H., Su, H., Yan, L., Li, J., and Li, W.X., ACS Catal., 2015, vol. 5, p. 3620.
Zhang, X., Li, Z., Guo, Q., Zheng, H., and Xie, K., Fuel Process. Technol., 2010, vol. 91, p. 379.
Savost’yanov, A.P., Yakovenko, R.E., Narochnyi, G.B., Sulima, S.I., Bakun, V.G., Soromotin, V.N., and Mitchenko, S.A., Catal. Commun., 2017, vol. 99, p. 25.
Savost’yanov, A.P., Narochnyi, G.B., Yakovenko, R.E., Mitchenko, S.A., and Zubkov, I.N., Pet. Chem., 2018, vol. 58, p. 76.
Savost’yanov, A.P., Yakovenko, R.E., Narochnyi, G.B., Bakun, V.G., Sulima, S.I., Yakuba, E.S., and Mitchenko, S.A., Kinet. Catal., 2017, vol. 58, p. 81.
Narochnyi, G.B., Yakovenko, R.E., Savost’yanov, A.P., and Bakun, V.G., Catal. Ind., 2016, vol. 8, p. 139.
Savost’yanov, A.P., Yakovenko, R.E., Sulima, S.I., Bakun, V.G., Narochnyi, G.B., Chernyshev, V.M., and Mitchenko, S.A., Catal. Today, 2017, vol. 279, p. 107.
Borg, Ø., Dietzel, P.D.C., Spjelkavik, A.I., Tveten, E.Z., Walmsley, J.C., Diplas, S., Eri, S., Holmen, A., and Rytter, E., J. Catal., 2008, vol. 259, p. 161.
Yakovenko, R.E., Zubkov, I.N., Narochnyi, G.B., Papeta, O.P., Denisov, O.D., and Savost’yanov, A.P., Kinet. Catal., 2020, vol. 61, p. 310.
Sulima, S.I., Bakun, V.G., Yakovenko, R.E., Shabel’skaya, N.P., Saliev, A.N., Narochnyi, G.B., and Savost’yanov, A.P., Kinet. Catal., 2018, vol. 59, p. 218.
Yakovenko, R.E., Savost’yanov, A.P., Narochniy, G.B., Soromotin, V.N., Zubkov, I.N., Papeta, O.P., Svetogorov, R.D., and Mitchenko, S.A., Catal. Sci. Technol., 2020, vol. 10, p. 7613.
Shafer, W.D., Gnanamani, M.K., Graham, U.M., Yang, J., Masuku, C.M., Jacobs, G., and Davis, B.H., Catalysts, 2019, vol. 9, p. 259.
Kasht, A., Hussain, R., Ghouri, M., Blank, J., and Elbashir, N.O., Am. J. Anal. Chem., 2015, vol. 6, p. 659.
PDF-2. The Powder Diffraction File TM. International Center for Diffraction Data (ICDD), PDF-2 Release, 2012. www.icdd.com.
Young, R.A., The Rietveld Method, Oxford: Oxford University, 1995, p. 298.
Savost’yanov, A.P., Yakovenko, R.E., Narochnyi, G.B., Zubkov, I.N., Sulima, S.I., Soromotin, V.N., and Mitchenko, S.A., Pet. Chem., 2018, vol. 60, p. 81.
Todic, B., Ma, W., Jacobs, G., Davis, B.H., and Bukur, D.B., J. Catal., 2014, vol. 311, p. 325.
Niu, C., Xia, M., Chen, C., Ma, Z., Jia, L., Hou, B., and Li, D., Appl. Catal., A, 2020, vol. 601, p. 117630.
Rytter, E., Tsakoumis, N.E., and Holmen, A., Catal. Today, 2016, vol. 261, p. 3.
Okoye-Chine, C.G., Moyo, M., Liu, X., and Hildebrandt, D., Fuel Process. Technol., 2019, vol. 192, p. 105.
Ao, M., Pham, G.H., Sunarso, J., Tade, M.O., and Liu, S., ACS Catal., 2018, vol. 8, p. 7025.
Luk, H.T., Mondelli, C., Ferre, D.C., Stewart, J.A., and Pérez -Ramirez, J., Chem. Soc. Rev., 2017, vol. 46, p. 1358.
Bhatelia, T., Li, C., Sun, Y., Hazewinkel, P., Burke, N., and Sage, V., Fuel Process. Technol., 2017, vol. 125, p. 277.
Wang, B., Liang, D., Guan, Z., Li, D., and Zhang, R., J. Phys. Chem., 2020, vol. 124, p. 5749.
Lebarbier, V.M., Mei, D., Kim, D.H., Andersen, A., Male, J.L., Holladay, J.E., Rousseau, R., and Wang, Y., J. Phys. Chem., C, 2011, vol. 115, p. 17440.
Zhao, Z., Lu, W., Yang, R., Zhu, H., Dong, W., Sun, F., Jiang, Z., Lyu, Y., Liu, T., Du, H., and Ding, Y., ACS Catal., 2018, vol. 8, p. 228.
Mahdavi, V., Peyrovi, M.H., Islami, M., and Mehr, J.Y., Appl. Catal., A, 2005, vol. 281, p. 259.
Han, S.J., Park, G., Lee, Y.-J., Jun, K.-W., Kim, S.K., Kim, Y.T., and Kwa, G., Mol. Catal., 2019, vol. 475, p. 110481.
Funding
This study was supported by the Russian Foundation for Basic Research (project no. 20-33-90149) and the Ministry of Science and Higher Education of the Russian Federation (state assignment no. 2019-0990) and carried out using the equipment of the Center for Shared Use “Nanotechnologies” at the Platov South-Russian State Polytechnic University (NPI).
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Translated by V. Makhlyarchuk
Abbreviations and notation: GHSV, gas hourly space velocity; SEM, scanning electron microscopy; XRD, X-ray diffraction.
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Zubkov, I.N., Soromotin, V.N., Savost’yanov, A.P. et al. Production of Alcohols and Olefins from CO and H2 on a Cobalt Catalyst at High Pressures and in the Gas Circulation Mode. Kinet Catal 63, 218–225 (2022). https://doi.org/10.1134/S0023158422020148
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DOI: https://doi.org/10.1134/S0023158422020148