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Extraction of rare earths and scandium by 2-phosphorylphenoxyacetic acid amides in the presence of ionic liquids

  • Physical Chemistry of Solutions
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Abstract

The distribution of Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Sc between aqueous solutions of their salts and solutions of 2-phosphorylphenoxy acid amides in dichloroethane containing an ionic liquid (1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide) have been studied. Metal ion extraction has been found to increase considerably in the presence of this ionic liquid in the organic phase. The stoichiometries of extractable complexes have been determined. The influence of aqueous HNO3 concentration and of the nature of extractant and ionic liquid on the efficiency of REE(III) and scandium(III) recovery to the organic phase has been considered.

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Authors and Affiliations

  1. Institute of Solid-State Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia

    A. N. Turanov

  2. Institute of Problems of Microelectronic Technologies and High Purity Materials, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia

    V. K. Karandashev

  3. Institute of Physiologically Active Compounds, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia

    V. E. Baulin

  4. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    V. E. Baulin, I. P. Kalashnikova & A. Yu. Tsivadze

  5. Ural Federal University Named after Eltsin, the First President of Russia, Yekaterinburg, Russia

    E. V. Kirillov, S. V. Kirillov & V. N. Rychkov

Authors
  1. A. N. Turanov
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  2. V. K. Karandashev
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  3. V. E. Baulin
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  4. I. P. Kalashnikova
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  5. E. V. Kirillov
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  6. S. V. Kirillov
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  7. V. N. Rychkov
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  8. A. Yu. Tsivadze
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Correspondence to A. N. Turanov.

Additional information

Original Russian Text © A.N. Turanov, V.K. Karandashev, V.E. Baulin, I.P. Kalashnikova, E.V. Kirillov, S.V. Kirillov, V.N. Rychkov, A.Yu. Tsivadze, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 3, pp. 396-402.

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Turanov, A.N., Karandashev, V.K., Baulin, V.E. et al. Extraction of rare earths and scandium by 2-phosphorylphenoxyacetic acid amides in the presence of ionic liquids. Russ. J. Inorg. Chem. 61, 377–383 (2016). https://doi.org/10.1134/S0036023616030232

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  • DOI: https://doi.org/10.1134/S0036023616030232

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