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New structural type in the chemistry of bismuth(III) polynuclear halide complexes: Synthesis and crystal structure of (H3O)3(diquat)6{[BiBr5]}6[BiBr6] • 2H2O

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Abstract

Complex (H3O)3(diquat)6{[BiBr5]}6[BiBr6] • 2H2O (I) has been prepared by the reaction between [BiBr6]3– and diaqua(1,1'-diethylene-2,2'-bipyridynium dibromide) in 2 M HBr and has been characterized by X-ray diffraction. The anionic part of compound I is formed by coordination polymeric anions {[BiBr5]–} n built of {BiBr6} octahedral blocks, which are joined by the μ2-bridge bromide ligands into infinite zigzag chains. The resulting complex belongs to new structural type among bismuth halide complexes.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Branch, prospect Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    S. A. Adonin, D. G. Samsonenko, I. V. Korol’kov, M. N. Sokolov & V. P. Fedin

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    S. A. Adonin, I. D. Gorokh, D. G. Samsonenko, I. V. Korol’kov, M. N. Sokolov & V. P. Fedin

Authors
  1. S. A. Adonin
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  2. I. D. Gorokh
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  3. D. G. Samsonenko
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  4. I. V. Korol’kov
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  5. M. N. Sokolov
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  6. V. P. Fedin
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Corresponding author

Correspondence to S. A. Adonin.

Additional information

Original Russian Text © S.A. Adonin, I.D. Gorokh, D.G. Samsonenko, I.V. Korol’kov, M.N. Sokolov, V.P. Fedin, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 8, pp. 1006–1011.

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Adonin, S.A., Gorokh, I.D., Samsonenko, D.G. et al. New structural type in the chemistry of bismuth(III) polynuclear halide complexes: Synthesis and crystal structure of (H3O)3(diquat)6{[BiBr5]}6[BiBr6] • 2H2O. Russ. J. Inorg. Chem. 61, 958–963 (2016). https://doi.org/10.1134/S0036023616080027

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  • DOI: https://doi.org/10.1134/S0036023616080027

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