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Immobilization of Heterocycle-Appended Porphyrins on UiO-66 and UiO-67 MOFs

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Abstract

An approach to immobilization of heterocycle-appended porphyrins bearing one or two anchoring groups at the surface of UiO-66 and UiO-67 MOFs has been developed. For this purpose, carboxy-substituted porphyrin’s derivatives Ni-4 and Ni-5 have been synthesized for the first time. It has been shown that the presence of one anchoring carboxy group at the periphery of the porphyrin is insufficient for the efficient immobilization. At the same time, the prepared pyrazinoporphyrin bearing two carboxy groups is efficiently immobilized at the surface of the MOF particles in 1 : 16 ratio with respect to hexanuclear Zr(IV) node clusters. The post-synthetic modification has been found to be the most efficient approach to prepare the target hybrid materials. The prepared materials are completely characterized by means of powder X-ray diffraction, scanning electron microscopy, and UV-vis diffuse reflectance and IR spectroscopies.

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ACKNOWLEDGMENTS

Analytical work was carried out on the equipment of the Shared Facility Centers for Physical Methods of Investigation at IPCE RAS and IGIC RAS.

Funding

The work was supported by the Russian Foundation for Basic Research (project no. 19-33-70036, synthesis of Ni-4 and Ni-5) and the Council for Grants of the President of the Russian Federation (grant MK-1454.2019.3, synthesis of hybrid materials).

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    K. P. Birin, I. A. Abdulaeva, D. A. Polivanovskaya, A. A. Sinel’shchikova, L. I. Demina, Yu. G. Gorbunova & A. Yu. Tsivadze

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    L. I. Demina, A. E. Baranchikov, Yu. G. Gorbunova & A. Yu. Tsivadze

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  1. K. P. Birin
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  2. I. A. Abdulaeva
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  3. D. A. Polivanovskaya
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  4. A. A. Sinel’shchikova
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  7. Yu. G. Gorbunova
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  8. A. Yu. Tsivadze
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Correspondence to K. P. Birin.

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Translated by G. Kirakosyan

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Birin, K.P., Abdulaeva, I.A., Polivanovskaya, D.A. et al. Immobilization of Heterocycle-Appended Porphyrins on UiO-66 and UiO-67 MOFs. Russ. J. Inorg. Chem. 66, 193–201 (2021). https://doi.org/10.1134/S0036023621020029

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