Abstract
A comparative study is performed of the catalytic activity of nanosized nickel deposited on detonation synthesis nanodiamond (DND) and coal (CSUG) produced by burning sugar and crystalline quartz in the hydrogenation of acetylene. Nanosized nickel is obtained through the thermal decomposition of nickel formate under a dynamic vacuum. The catalysts are studied by means of scanning electron and transmission electron microscopy, X-ray fluorescence, IR-spectroscopy, X-ray diffraction, and pulse microcatalytic method. It is shown that Ni/DND is an active catalyst of acetylene hydrogenation, considerably surpassing Ni/quartz and Ni/CSUG. The apparent activation energy of the hydrogenation of acetylene is calculated, and the region of the reaction are determined for all catalysts. It is found that the influence of the structure and nature of a functional coating of nanodiamond on the catalytic activity of Ni/DND deposited catalyst in the hydrogenation of acetylene. The ability of Ni/DND to hold active hydrogen is detected.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
D. S. Su, J. Zhang, B. Frank, et al., ChemSusChem 3, 169 (2010).
D. S. Su, N. I. Maksimova, G. Mestl, et al., Carbon 45, 2145 (2007).
J. Zhang, D. S. Su, A. Zhang, et al., Angew. Chem. 119, 7460 (2007); Angew. Chem. Int. Ed. 46, 7319 (2007).
E. A. Tveritinova, I. I. Kulakova, Yu. N. Zhitnev, et al., Russ. J. Phys. Chem. A 86, 26 (2012).
V. Yu. Dolmatov, Detonation Nanodiamonds. Production, Properties, Application (Professional, St. Petersburg, 2011), p. 534 [in Russian].
O. A. Shenderova, V. V. Zhirnov, and D. W. Brenner, Crit. Rev. Sol. State Mater. Sci 27, 227 (2002).
A. Mavrodinova, M. Popova, I. Kolev, et al., Appl. Surf. Sci. 253, 7115 (2007).
V. Mavrodinova, M. Popova, D. Mitev, et al., Catal. Commun. 8, 1502 (2007).
S. A. Kachevskii, E. V. Golubina, E. S. Lokteva, and V. V. Lunin, Russ. J. Phys. Chem. 81, 866 (2007).
J. L. Figueiredo, M. Fernando, and R. Pereira, Catal. Today 150, 2 (2010).
Yu. A. Ryndin, O. S. Alexeev, P. A. Simonov, et al., J. Mol. Catal. 55, 109 (1989).
O. V. Turova, E. V. Starodubtseva, M. G. Vinogradov, et al., Catal. Commun. 12(7), 577 (2011).
M. Zielinski, R. Wojcieszak, S. Monteverdi, et al., Catal. Commun. 6, 777 (2005).
W. C. Conner and J. L. Falconer, Chem. Rev. 95, 759 (1995).
Yu. N. Zhitnev, E. A. Tveritinova, F. M. Spiridonov, and V. V. Lunin, Russ. J. Phys. Chem. A 84, 1127 (2010).
J. Geng and C. Singh, R. Chem. Commun., 2666 (2002).
Yu. N. Zhitnev, E. A. Tveritinova, and V. V. Lunin, Russ. J. Phys. Chem. A 82, 140 (2008).
D. W. Bassett and H. W. Habgood, J. Phys. Chem. 64, 769 (1960).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.A. Tveritinova, I.I. Kulakova, Yu.N. Zhitnev, A.N. Kharlanov, A.V. Fionov, W. Chen, I. Buyanova, V.V. Lunin, 2013, published in Zhurnal Fizicheskoi Khimii, 2013, Vol. 87, No. 7, pp. 1138–1145.
Rights and permissions
About this article
Cite this article
Tveritinova, E.A., Kulakova, I.I., Zhitnev, Y.N. et al. Effect of the detonation nanodiamond surface on the catalytic activity of deposited nickel catalysts in the hydrogenation of acetylene. Russ. J. Phys. Chem. 87, 1114–1120 (2013). https://doi.org/10.1134/S0036024413070352
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024413070352