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Aggregation behavior and catalytic properties of systems based on aminomethylated calix[4]resorcinarenes and poly(ethylene) imines

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Abstract

Self-assembling in systems poly(ethylene) imine-aminomethylated calix[4]resorcinarene-water-DMF (30 vol%) and catalytic properties of these compositions in hydrolysis of 4-nitrophenylbis (chloromethyl)phosphinate are studied. Critical concentrations of association, aggregates radii, and kinetic parameters of the reaction are established.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Tatarstan, Russia

    T. N. Pashirova, S. S. Lukashenko, E. M. Kosacheva, M. V. Leonova, L. I. Vagapova, A. R. Burilov, M. A. Pudovik, L. A. Kudryavtseva & A. I. Konovalov

Authors
  1. T. N. Pashirova
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  2. S. S. Lukashenko
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  3. E. M. Kosacheva
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  4. M. V. Leonova
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  5. L. I. Vagapova
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  6. A. R. Burilov
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  7. M. A. Pudovik
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  8. L. A. Kudryavtseva
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  9. A. I. Konovalov
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Correspondence to E. M. Kosacheva.

Additional information

Original Russian Text © T.N. Pashirova, S.S. Lukashenko, E.M. Kosacheva, M.V. Leonova, L.I. Vagapova, A.R. Burilov, M.A. Pudovik, L.A. Kudryavtseva, A.I. Konovalov, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 3, pp. 417–424.

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Pashirova, T.N., Lukashenko, S.S., Kosacheva, E.M. et al. Aggregation behavior and catalytic properties of systems based on aminomethylated calix[4]resorcinarenes and poly(ethylene) imines. Russ J Gen Chem 78, 402–409 (2008). https://doi.org/10.1134/S1070363208030109

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  • DOI: https://doi.org/10.1134/S1070363208030109

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