Abstract
Ozone was concentrated in ССl4 matrix at successive cooling. It has been shown that absorption spectra of ozone in ССl4 (λmax 258 nm) are practically identical to these in an aqueous solution. Vibrational structure typical of gaseous ozone over the Chappuis range has been retained. Position and shape of the bands for the О3–ССl4 system are independent of temperature. Molar absorptivity of the Chappuis band has been measured (ε600 8.0±0.3 M–1 cm–1), on the basis of which limiting solubility of ozone in the CCl4 at 760 mmHg has been determined.
Similar content being viewed by others
References
Razumovskii, S.D. and Zaikov, G.E., Bull. Acad. Sci. USSR. Div. Chem. Sci., 1971, vol. 20, no. 4, p. 616. doi 10.1007/BF00853885
Borodin, A.A. and Razumovskii, S.D., Kinetics and Catalysis, 2009, vol. 50, no. 3, p. 385. doi 10.1134/S0023158409030070
Aleksandrov, Yu.A., Tarunin, B.I., and Perepletchikov, M.L., Zh. Obshch. Khim., 1976, vol. 46, no. 1, p.3.
Shiyin, L., Yiping, Zh., Xiaorong, L., Guoxiang, W., and Lixiao, N., Bull. Env. Contamin. Toxicol., 2011, vol. 87, no. 3, p. 297. doi 10.1007/s00128-011-0352-6
Ward, D.B., Tizaoui, C., and Slater, M.J., Ozone: Sci. Eng., 2003, vol. 25, no. 6, p. 485. doi 10.1080/01919510390481793
Aleksandrov, Yu.A., Tarunin, B.I., and Perepletchikov, M.L., Zh. Fiz. Khim., 1983, vol. 57, no. 10, p. 2385.
Bin, A.K., Ozone: Sci. Eng., 2006, vol. 28, no. 2, p. 67. doi 10.1080/01919510600558635
Ershov, B.G. and Panich, N.M., Doklady Phys. Chem., 2015, vol. 465, no. 1, p. 279. doi 10.1134/S0012501615110068
Peters, D.G., Hayes, J.M., and Hieftje, G.M., Chemical Separations and Measurements: Theory and Practice of Analytical Chemistry, Science, 1974.
Bader, H. and Hoigne, J., Ozone: Sci. Eng., 1982, vol. 4, no. 4, p. 169. doi 10.1080/01919518208550955
Nobbs, J. and Tizaoui, C., Ozone: Sci. Eng., 2014, vol. 36, p. 110. doi 10.1080/01919512.2013.836956
Nakagawa, T.W., Andrews, L.J., and Keefer, R.M., J. Am. Chem. Soc., 1960, vol. 82, no. 2, p. 269. doi 10.1021/ja01487a004
Choi Young-Ik and Hong Andrew, Korean J. Chem. Eng., 2007, vol. 24, no. 6, p. 1003. doi 10.1007/s11814-007-0111-x
Lunin, V.V., Popovich, M.P., and Tkachenko, S.N., Fizicheskaya khimija ozona (Physical Chemistry of Ozone), Moscow: MGU, 1998.
Ershov, B.G., Gordeev, A.V., and Seliverstov, A.F., Ozone: Sci. Eng., 2017, vol. 39, no. 2, p. 69. doi 10.1080/01919512.2016.1262239
Tachikawa, H. and Abe, S., Inorg. Chem., 2003, vol. 42, no. 7, p. 2188. doi 10.1021/ic0207101
Teramoto, M., Ito, T., and Teranishi, H., J. Chem. Eng. Japan, 1977, vol. 10, no. 3, p. 218. doi 10.1252/jcej.10.218
Matvienko, V.G. and Nifantova, L.S., Nauchn. Tr. DonNTU, Ser. Khim. Khim. Tekhnol., 2008, no. 134(10), p. 32.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.M. Panich, B.G. Ershov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 6, pp. 889–894.
Rights and permissions
About this article
Cite this article
Panich, N.M., Ershov, B.G. Optical Properties and Solubility of Ozone in CCl4 at Low Temperature. Russ J Gen Chem 88, 1071–1075 (2018). https://doi.org/10.1134/S1070363218060038
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363218060038