Abstract
The supramolecular self-assembly in mixed low-concentrated aqueous solutions of chitosan and sulfonated metallophthalocyanines was examined by spectroscopic and dynamic light scattering techniques. The research subjects were Cu(II) and Co(II) tetrasulfophthalocyaninates, as well as Cu(II) phthalocyaninate containing sulfonate groups and a vinylsulfonic substituent. The resulting supramolecular complexes were characterized by a reproducible stoichiometric composition, as well as by the ability to move slowly into a colloidal-dispersed state. Phase separation was preceded by a metastable state with unchanging spectral characteristics, for which the size and ζ-potential of the primary supramolecular particles were determined.
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Gol’dshleger, N.V., Baulin, V.E., and Tsivadze, A.Yu., Protect. Met. Phys. Chem. Surf., 2014, vol. 50, no. 2, pp. 135–172. doi https://doi.org/10.7868/S0044185614020089
Lukyanets, E.A. and Nemykin, V.N., J. Porph. Phthal., 2010, vol. 14, pp. 1–40. doi https://doi.org/10.1142/S108842461000188X
Kimura, M., Yamaguchi, Y., and Koyama, T., J. Porph. Phthal., 1997, no. 4, pp. 309–313. doi 10.1002/(SICI)1099-1409(199710)1:4
Tao, X., Ma, W., Zhang, T., and Zhao, J., Angew. Chem. Int. Ed., 2001, vol. 40, no. 16, pp. 3014–3016. doi 10.1002/1521-3773(20010817)40:16
Wang, R.M., Wang, H., Wang, Y., Li, H.R., He, Y.F., and Hao, E.X., Color. Technol., 2014, vol. 13, no. 1, pp. 32–38. doi https://doi.org/10.1111/cote.12062
Silva, A.T.B., Coelho, A.G., Lopes, L.C. da S., Martins, M.V.A., Crespilho, F. N., Merkoçid, A., and da Silva, W.C., J. Braz. Chem. Soc., 2013, vol. 24, no. 8, pp. 1237–1245. doi https://doi.org/10.5935/0103-5053.20130157
Baek, S.Y. and Na, K., J. Colloids Surf. B: Biointerfaces, 2013, vol. 101, pp. 493–500. doi https://doi.org/10.1016/j.colsurfb.2012.06.036
Kozlyak, E.I., Erokhin, A.S., and Yatsimirskii, A.K., Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986, vol. 35, no. 4, p. 741. doi https://doi.org/10.1007/BF00954219
Zelina, J.P., Njue, C.K., Rusling, J.F., Kamau, G.N., Masila, M., and Kibugu, J., J. Porph. Phthal., 1999, vol. 3, no. 3, pp. 188–199. doi 10.1002/(SICI)1099-1409(199903)3:3
Hu, N.F., Howe, D.J., Ahmadi, M.F., and Rusling, J.F., Anal. Chem., 1992, vol. 64, no. 24, pp. 3180. doi https://doi.org/10.1021/ac00048a016
Monajjemi, M., Aghaie, H., and Naderi, F., Biochemistry, 2007, vol. 72, no. 6, pp. 652–657. doi https://doi.org/10.1134/S0006297907060089
Muzzarelli, R.A.A. and Muzzarelli, C., Adv. Polym. Sci., 2005, vol. 186, pp. 151–209. doi https://doi.org/10.1007/b136820
Rinaudo, M., Chitin and Chitosan: Properties and Applications, Prog. Polym. Sci., 2006, no. 31, pp. 603–632. doi https://doi.org/10.1016/j.progpolymsci.2006.06.001
Khitin i khitozan: poluchenie, svoistva, primenenie (Chitin and Chitosan: Production, Properties, and Application), Skryabin, K.G., Vikhoreva, G.A., and Varlamov, V.P., Eds., Moscow: Nauka, 2002.
Lipatova, I.M., Mezina, E.A., and Butina, Yu.V., Russ. J. Appl. Chem., 2013, vol. 86, no. 4, p. 575. doi https://doi.org/10.1134/S1070427213040216
Synytsya, A., Synytsya, A., Blafkova, P., Ederová, J., Spevacek, J., Slepicka, P., Kral, V., and Volka, K., Biomacromolec., 2009, vol. 10, no. 5, p. 1067. doi https://doi.org/10.1021/bm8011715
Synytsya, A., Synytsya, A., Blafkova, P., Volka, K., and Vladimir, K., Spectrochim. Acta, Part A, 2007, vol. 66, no. 1, p. 225. doi https://doi.org/10.1016/j.saa.2006.02.046
Wang, W., Bo, S., Li, S., and Qin, W., Int. J. Biol. Macromol., 1991, vol. 13, no. 5, pp. 281–285. doi https://doi.org/10.1016/0141-8130(91)90027-R
Shigemasa, Y., Matsuura, H., Sashiwa, H., and Saimoto, H., Int. J. Biol. Macromol., 1996, vol. 18, no. 3, pp. 237–242. doi https://doi.org/10.1016/0141-8130(95)01079-3.
Kulinich, V.P., Shaposhnikov, G.P., Gorelov, V.N., and Chernyaeva, E.A., Russ. J. Gen. Chem., 2006, vol. 76, no. 8, pp. 1331–1336. doi https://doi.org/10.1134/S1070363206080317
Shaposhnikov, G.P., Maizlish, V.E., and Kulinich, V.P., Modifitsirovannye ftalotsianiny i ikh strukturnye analogi (Modified Phthalocyanines and Their Structural Analogs), Moscow: Krasand, 2012.
Bekturov, R.E. and Legkunets, E.A., Assotsiatsiya polimerov s malymi molekulami (Association of Polymers with Small Molecules), Alma-Ata: Nauka, 1983, pp. 14–37.
Snow, A.W., Phthalocyanine Aggregation, in Porphyrin Handbook, Kadish, K., Smith, K., and Guilard, R., Eds., New York: Elsevier Science, 2003, vol. 17, pp. 129–177. doi https://doi.org/10.1016/B978-0-08-092391-8.50009-1
Gruen, L.C. and Blagrove, R.J., Aust. J. Chem. Soc., 1973, vol. 26, no. 2, pp. 319–323. doi https://doi.org/10.1071/CH9730319
Bernauer, K. and Fallab, S., Helv. Chim. Acta, 1961, vol. 44, no. 5, pp. 1287–1292.
McLendon, G. and Martell, A.E., Inorg. Chem., 1977, vol. 16, no. 7, pp. 1812–1813.
Bobreshova, O.V., Bobylkina, O.V., Kulentsov, P.I., Bobrinskaya, G.A., Varlamov, V.P., and Nemtsev, S.V., Russ. J. Electrochem., 2004, vol. 40, no. 7, pp. 694–697. doi https://doi.org/10.1023/B:RUEL.0000035250.54523.e8.
Kasha, M., Rawls, H.R., and El-Bayoumi, M.A., Pure Appl. Chem., 1965, vol. 11, nos. 3–4, pp. 371–392. https://doi.org/www.iupac.org/publications/pac/pdf/1965/pdf/1103x0371.pdf.
Ahrens, U. and Kuhn, H., Z. Phys. Chem. Neue Folge, 1963, vol. 37, pp. 1–32.
Kozlov, V.A., Berezin, B.D., and Popkova, I.A., Zh. Fiz. Khim., 1981, vol. 55, no. 6, pp. 1481–1486.
Jiang, H., Liang, J., Grant, J.T., Su, W., Bunning, T. J., Cooper, T.M., and Adams, W.W., Macromol. Chem. Phys., 1997, vol. 198, no. 5, pp. 1561–1578. doi https://doi.org/10.1002/macp.1997.021980519
Zhang, Y. H., Chen, D.M., He, T., and Liu, F.-C., Spectrochim. Acta, Part A, 2003, vol. 59, no. 1, pp. 87–101. doi https://doi.org/10.1016/S1386-1425(02)00124-5
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Lipatova, I.M., Mezina, E.A. & Yusova, A.A. Supramolecular Self-Assembly and Phase Transformations in Aqueous Systems Based on Chitosan and Sulfonated Metallophthalocyanines. Russ J Gen Chem 89, 612–618 (2019). https://doi.org/10.1134/S1070363219030423
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DOI: https://doi.org/10.1134/S1070363219030423