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Synthesis of Molybdenum Chelate-Bonded Fe3O4 Nanoparticles and Their Efficient Catalytic Activity in Epoxidation of Alkenes

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Abstract

Immobilization of Mo(VI) ions on magnetic nanoparticles has been performed using surface modification of Fe3O4 with 2-hydroxy-5-(2-nitrophenyldiazenyl)benzaldehyde (HNPABA). The new nanomagnetic-supported organocatalyst (Fe3O4@SiO2−HNPABA−Mo(VI)) has been applied in epoxidation of olefins with tert-butyl hydroperoxide. The results indicate that Fe3O4@SiO2−HNPABA−Mo(VI) magnetic nanoparticles demonstrate excellent activity and high stability. The effect of several parameters such as a solvent, catalyst, oxidant content, and temperature has been studied. In addition, the catalyst could be repeatedly applied up to five times without loss of activity in epoxidation of alkenes.

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ACKNOWLEDGMENTS

We are sincerely grateful to the Khorramabad Branch, Islamic Azad University for support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Khorramabad Branch, Islamic Azad University, 6817816645, Khorramabad, Iran

    S. Menati & E. Mohseni

  2. Department of Chemistry, Shoushtar Branch, Islamic Azad University, 6451741117, Shoushtar, Iran

    M. Gorjizadeh

  3. Department of Chemistry, Mahshahr Branch, Islamic Azad University, 6351977439, Mahshahr, Iran

    S. Sayyahi

Authors
  1. S. Menati
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  2. E. Mohseni
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  3. M. Gorjizadeh
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  4. S. Sayyahi
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Correspondence to S. Menati or S. Sayyahi.

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Menati, S., Mohseni, E., Gorjizadeh, M. et al. Synthesis of Molybdenum Chelate-Bonded Fe3O4 Nanoparticles and Their Efficient Catalytic Activity in Epoxidation of Alkenes. Russ J Gen Chem 91, 1789–1793 (2021). https://doi.org/10.1134/S1070363221090267

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  • DOI: https://doi.org/10.1134/S1070363221090267

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