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Improvement of procedures for preparing Tetrafluoroethane-β-sultone and fluorocarbonyldifluoromethanesulfonyl fluoride

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Synthesis of tetrafluoroethane-β-sultone by the reaction of tetrafluoroethylene with sulfuric anhydride and of fluorocarbonyldifluoromethanesulfonyl fluoride by catalytic reaction of tetrafluoroethylene with sulfuric anhydride using BAU-2, SKT-6, or AG-3 activated carbon as catalyst was studied. The possibility of replacing sulfuric anhydride prepared by distillation from oleum by sulfuric anhydride prepared by sulfur dioxide oxidation was demonstrated.

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References

  1. Knunyants, I.L. and Yakobson, G.G., Sintezy ftororganicheskikh soedinenii (Synthesis of Fluorinated Organic Compounds), Moscow: Khimiya, 1973.

    Google Scholar 

  2. Belyaev, M.A., Knunyants, I.L., and Sokol’skii, G.A., Dokl. Akad. Nauk SSSR, 1986, no. 12, pp. 1613–1616.

    Google Scholar 

  3. Novoe v tekhnologii soedinenii ftora (Fluorine Compounds. Modern Techonology and Application), Ishikawa, N., Ed., Moscow: Mir, 1984.

    Google Scholar 

  4. Maksimov, B.N., Barabanov, V.G., Serushkin, I.L., et al., Promyshlennye ftororganicheskie soedineniya (Commercial Fluorinated Organic Compounds), Leningrad: Khimiya, 1990.

    Google Scholar 

  5. Barabanov, V.G., Bispen, T.A., Vasil’ev, A.S., et al., Ftorn. Zametki, 2011, no. 2 (75), http://notes.fluorine1.ru/public/2011/2-2011/letters/rusletter4.html

    Google Scholar 

  6. Knuniants, I.L. and Sokolski, G.A., Angew. Chem. Int. Ed., 1972, vol. 11, no. 7, pp. 583–595.

    Article  Google Scholar 

  7. RF Patent 2417982, Publ. 2011.

  8. Amelin, A.G., Proizvodstvo sernoi kisloty (Production of Sulfuric Acid), Moscow: Khimiya, 1967.

    Google Scholar 

  9. Kuznetsov, D.A., Proizvodstvo sernoi kisloty (Production of Sulfuric Acid), Moscow: Trudrezervizdat, 1947.

    Google Scholar 

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Authors and Affiliations

  1. Applied Chemistry Russian Scientific Center, ul. Krylenko 26A, St. Petersburg, 193232, Russia

    V. G. Barabanov, T. A. Bispen, V. V. Kornilov, D. D. Moldavskii, A. S. Odinokov & I. M. Fenichev

Authors
  1. V. G. Barabanov
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  2. T. A. Bispen
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  3. V. V. Kornilov
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  4. D. D. Moldavskii
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  5. A. S. Odinokov
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  6. I. M. Fenichev
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Corresponding author

Correspondence to V. G. Barabanov.

Additional information

Original Russian Text © V.G. Barabanov, T.A. Bispen, V.V. Kornilov, D.D. Moldavskii, A.S. Odinokov, I.M. Fenichev, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 5, pp. 630–635.

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Barabanov, V.G., Bispen, T.A., Kornilov, V.V. et al. Improvement of procedures for preparing Tetrafluoroethane-β-sultone and fluorocarbonyldifluoromethanesulfonyl fluoride. Russ J Appl Chem 87, 619–623 (2014). https://doi.org/10.1134/S1070427214050140

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  • DOI: https://doi.org/10.1134/S1070427214050140

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