Abstract
A model of the heterogeneous catalysis of the combustion of condensed systems based on an analysis of local changes in the burning velocity of the condensed phase of the propellant was developed. The model expresses the catalyst efficiency through the concentration and particle size of the catalyst and the uncatalyzed propellant burning velocity. Two experimentally determined parameters were introduced to characterize the effect of the chemical properties of the propellant system. The catalysis efficiency was demonstrated to tend to finite limits at d → 0 and U 0 → 0. This model for the first time made it possible to correctly describe a wide variety of experimentally observed regularities.
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References
A. F. Belyaev and N. N. Bakhman, Combustion of Heterogeneous Condensed Systems (Nauka, Moscow, 1967) [in Russian].
V. B. Librovich, Zh. Prikl. Mekh. Tekh. Fiz., No. 4, 33 (1962).
N. Kubota and T. Masumoto, in Proc. 16th Intern. Symp. on Combustion (The Combust. Inst., Pittsburgh, 1976), p. 1201.
V. A. Strunin and G. B. Manelis, Fiz. Goreniya Vzryva, No. 5, 24 (1979).
L. K. Gusachenko, V. Yz. Zarko, V. Ya. Zyryanova, and V. P. Bobryshev, Modeling of the Combustion Processes for Solid Fuels (Nauka, Moscow, 1985) [in Russian].
F. S. Sokolovskii, Candidate’s Dissertation in Technical Science (IKhF AN SSSR, Moscow, 1975).
A. Kishore, Raketn. Tekhn. Kosmon. 17(11), 126 (1979).
Rocket Fuels, Collected vol., Ed. by S. A. Alemasov (Mir, Moscow, 1975), p. 188 [in Russian].
G. P. Melesov, Candidate’s Dissertation in Mathematics and Physics (IKhF AN SSSR, Moscow, 1971).
S. V. Chuiko, Doctoral Dissertation in in Mathematics and Physics (IKhF AN SSSR, Moscow, 1982).
D. Koen, Raketn. Tekhn. Kosmon. 18(8), 182 (1980).
S. V. Chuiko, F. S. Sokolovskii, and G. V. Nechai, Khim. Fiz. 16(2), 233 (1997).
O. P. Korobeinichev, A. S. Shmelev, and A. V. Tatevosyan, Fiz. Goreniya Vzryva 8, 378 (1972).
S. V. Chuiko, F. S. Sokolovskii, and G. V. Nechai, Khim. Fiz. 28(11), 49 (2009).
V. K. Bobolev, M. Ya. Gen, V. M. Mal’tsev, G. P. Melesov, et al., Fiz. Goreniya Vzryva 7, 366 (1971).
S. V. Chuiko, F. S. Sokolovskii, and G. V. Nechai, Khim. Fiz. 26(6), 48 (2007) [Russ. J. Phys. Chem. B 1, 236 (2007)].
B. Delmon, Reaction Kinetics in Heterogeneous Chemical Systems (Elsevier, New York, 1975; Mir, Moscow, 1972).
O. P. Korobeinichev, A. M. Viktorenko, and A. G. Tereshchenko, Fiz. Goreniya Vzryva 8, 511 (1972).
P. P. Popova, Candidate’s Dissertation in Technical Science (IKhF AN SSSR, Moscow, 1974).
A. Pitmen, Jr., Raketn. Tekhn. Kosmon. 7(2), 328 (1969).
O. I. Leipunskii, A. A. Zenin, and V. M. Puchkov, in Combustion and Explosion (Nauka, Moscow, 1972), p. 74 [in Russian].
K. Sabadel, D. Vinograd, and M. Sammerfild, Raketn. Tekhn. Kosmon. 3(9), 33 (1965).
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Original Russian Text © S.V. Chuiko, F.S. Sokolovskii, G.V. Nechai, 2010, published in Khimicheskaya Fizika, 2010, Vol. 29, No. 3, pp. 67–75.
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Chuiko, S.V., Sokolovskii, F.S. & Nechai, G.V. Model of the heterogeneous catalyst of the combustion of condensed systems. Russ. J. Phys. Chem. B 4, 256–264 (2010). https://doi.org/10.1134/S1990793110020119
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DOI: https://doi.org/10.1134/S1990793110020119