Skip to main content
SpringerLink
Log in

On the origin of multi-step spin transition behaviour in 1D nanoparticles

  • Regular Article
  • Published:
The European Physical Journal B Aims and scope Submit manuscript

Abstract

To investigate the spin state switching mechanism in spin crossover (SCO) nanoparticles, a special attention is given to three-step thermally induced SCO behavior in 1D chains. An additional term is included in the standard Ising-like Hamiltonian to account for the border interaction between SCO molecules and its local environment. It is shown that this additional interaction, together with the short range interaction, drives the multi-steps thermal hysteretic behavior in 1D SCO systems. The relation between a polymeric matrix and this particular multi-step SCO phenomenon is discussed accordingly. Finally, the environmental influence on the SCO system’s size is analyzed as well.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H.J. Shepherd, G. Molnar, W. Nicolazzi, L. Salmon, A. Bousseksou, Eur. J. Inorg. Chem. 2013, 653 (2013)

    Article  Google Scholar 

  2. A. Bousseksou, G. Molnar, L. Salmon, W. Nicolazzi, Chem. Soc. Rev. 40, 3313 (2011)

    Article  Google Scholar 

  3. P. Gutlich, A.B. Gaspar, Y. Garcia, Beilstein J. Org. Chem. 9, 342 (2013)

    Article  Google Scholar 

  4. A. Rotaru, I.Y.A. Gural’skiy, G. Molnar, L. Salmon, P. Demont, A. Bousseksou, Chem. Commun. 48, 4163 (2012)

    Article  Google Scholar 

  5. T. Sato, K. Nishi, S. Iijima, M. Kojima, N. Matsumoto, Inorg. Chem. 48, 7211 (2009)

    Article  Google Scholar 

  6. E. Coronado, J.R. Galan-Mascaros, M. Monrabal-Capilla, J. Garcia-Martinez, P. Pardo-Ibanez, Adv. Mater. 19, 1359 (2007)

    Article  Google Scholar 

  7. F. Volatron, L. Catala, E. Riviere, A. Gloter, O. Stephan, T. Mallah, Inorg. Chem. 47, 6584 (2008)

    Article  Google Scholar 

  8. D. Mader, S. Pillet, C. Carteret, M.-J. Stébé, J.-L. Blin, J. Dispers. Sci. Technol. 32, 1771 (2011)

    Article  Google Scholar 

  9. A. Tissot, J.-F. Bardeau, E. Rivière, F. Brisset, M.-L. Boillot, Dalton Trans. 39, 7806 (2010)

    Article  Google Scholar 

  10. A. Tissot, L. Rechignat, A. Bousseksou, M.-L. Boillot, J. Mater. Chem. 22, 3411 (2012)

    Article  Google Scholar 

  11. A.D. Naik, L. Stappers, J. Snauwaert, J. Fransaer, Y. Garcia, Small 6, 2842 (2010)

    Article  Google Scholar 

  12. T. Zhao, L. Cuignet, M.M. Dirtu, M. Wolff, V. Spasojevic, I. Boldog, A. Rotaru, Y. Garcia, C. Janiak, J. Mater. Chem. C 2015, 7802 (2015)

    Article  Google Scholar 

  13. A. Hauser, Ligand Field Theoretical Considerations, in Spin Crossover in Transition Metal Compounds I (Springer, 2004), p. 49

  14. J. Linares, E. Codjovi, Y. Garcia, Sensors 12, 4479 (2012)

    Article  Google Scholar 

  15. C.-M. Jureschi, I. Rusu, E. Codjovi, J. Linares, Y. Garcia, A. Rotaru, Physica B 449, 47 (2014)

    Article  ADS  Google Scholar 

  16. C. Jureschi, J. Linares, A. Rotaru, M. Ritti, M. Parlier, M. Dîrtu, M. Wolff, Y. Garcia, Sensors 15, 2388 (2015)

    Article  Google Scholar 

  17. N.F. Sciortino, K.R. Scherl-Gruenwald, G. Chastanet, G.J. Halder, K.W. Chapman, J.-F. Letard, C.J. Kepert, Angew. Chem. Int. Ed. 51, 10154 (2012)

    Article  Google Scholar 

  18. T. Kosone, I. Tomori, C. Kanadani, T. Saito, T. Mochida, T. Kitazawa, Dalton Trans. 39, 1719 (2010)

    Article  Google Scholar 

  19. K. Nishi, H. Kondo, T. Fujinami, N. Matsumoto, S. Iijima, M.A. Halcrow, Y. Sunatsuki, M. Kojima, Eur. J. Inorg. Chem. 2013, 927 (2013)

    Article  Google Scholar 

  20. J. Linares, H. Spiering, F. Varret, Eur. Phys. J. B 10, 271 (1999)

    Article  ADS  Google Scholar 

  21. D. Chiruta, J. Linares, M. Dimian, Y. Garcia, Eur. J. Inorg. Chem. 2013, 951 (2013)

    Article  Google Scholar 

  22. D. Chiruta, J. Linares, S. Miyashita, K. Boukheddaden, J. Appl. Phys. 115, 194309 (2014)

    Article  ADS  Google Scholar 

  23. K. Boukheddaden, J. Linares, H. Spiering, F. Varret, Eur. Phys. J. B 15, 317 (2000)

    Article  ADS  Google Scholar 

  24. M.M. Dirtu, A. Rotaru, D. Gillard, J. Linares, E. Codjovi, B. Tinant, Y. Garcia, Inorg. Chem. 48, 7838 (2009)

    Article  Google Scholar 

  25. M.M. Dirtu, C. Neuhausen, A.D. Naik, A. Rotaru, L. Spinu, Y. Garcia, Inorg. Chem. 49, 5723 (2010)

    Article  Google Scholar 

  26. C. Lochenie, W. Bauer, A.P. Railliet, S. Schlamp, Y. Garcia, B. Weber, Inorg. Chem. 53, 11563 (2014)

    Article  Google Scholar 

  27. M.M. Dîrtu, F. Schmit, A.D. Naik, I. Rusu, A. Rotaru, S. Rackwitz, J.A. Wolny, V. Schünemann, L. Spinu, Y. Garcia, Chemistry 21, 5843 (2015)

    Article  Google Scholar 

  28. J.A. Real, H. Bolvin, A. Bousseksou, A. Dworkin, O. Kahn, F. Varret, J. Zarembowitch, J. Am. Chem. Soc. 114, 4650 (1992)

    Article  Google Scholar 

  29. A. Bousseksou, J. Nasser, J. Linares, K. Boukheddaden, F. Varret, J. Phys. I 2, 1381 (1992)

    Google Scholar 

  30. J. Wajnflasz, R. Pick, J. Phys. Colloques 32, C1 (1971)

    Article  Google Scholar 

  31. D. Chiruta, J. Linares, M. Dimian, Y. Alayli, Y. Garcia, Eur. J. Inorg. Chem. 2013, 5086 (2013)

    Article  Google Scholar 

  32. D. Chiruta, J. Linares, Y. Garcia, M. Dimian, P.R. Dahoo, Physica B 434, 134 (2014)

    Article  ADS  Google Scholar 

  33. L. Stoleriu, P. Chakraborty, A. Hauser, A. Stancu, C. Enachescu, Phys. Rev. B 84, 134102 (2011)

    Article  ADS  Google Scholar 

  34. A. Atitoaie, R. Tanasa, C. Enachescu, J. Magn. Magn. Mater. 324, 1596 (2012)

    Article  ADS  Google Scholar 

  35. A. Muraoka, K. Boukheddaden, J. Linares, F. Varret, Phys. Rev. B 84, 054119 (2011)

    Article  ADS  Google Scholar 

  36. A. Rotaru, F. Varret, A. Gindulescu, J. Linares, A. Stancu, J. Létard, T. Forestier, C. Etrillard, Eur. Phys. J. B 84, 439 (2011)

    Article  ADS  Google Scholar 

  37. A. Tokarev, L. Salmon, Y. Guari, G. Molnar, A. Bousseksou, New J. Chem. 35, 2081 (2011)

    Article  Google Scholar 

  38. A. Tokarev, L. Salmon, Y. Guari, W. Nicolazzi, G. Molnar, A. Bousseksou, Chem. Commun. 46, 8011 (2010)

    Article  Google Scholar 

  39. J. Larionova, L. Salmon, Y. Guarl, A. Tokarev, K. Molvinger, G. Molnar, A. Bousseksou, Angew. Chem. Int. Ed. 47, 8236 (2008)

    Article  Google Scholar 

  40. D. Chiruta, C.-M. Jureschi, J. Linares, Y. Garcia, A. Rotaru, J. Appl. Phys. 115, 053523 (2014)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. GEMaC, Université de Versailles Saint-Quentin-en-Yvelines, CNRS-UVSQ (UMR 8635), 78035, Versailles Cedex, France

    Daniel Chiruta & Jorge Linares

  2. Faculty of Electrical Engineering and Computer Science &MANSiD, Stefan cel Mare University, 720229, Suceava, Romania

    Daniel Chiruta, Catalin-Maricel Jureschi & Aurelian Rotaru

  3. LISV, Université de Versailles Saint-Quentin-en-Yvelines, 78140, Velizy, France

    Catalin-Maricel Jureschi

  4. LATMOS, Université de Versailles-Saint-Quentin-en-Yvelines, Sorbonne Universités, CNRS-UMR 8190, 78280, Guyancourt, France

    Pierre Richard Dahoo

  5. Institute of Condensed Matter and Nanosciences, Molecules, Solids and Reactivity (IMCN/MOST), Université Catholique de Louvain, Place L. Pasteur 1, 1348, Louvain-la-Neuve, Belgium

    Yann Garcia

Authors
  1. Daniel Chiruta
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Catalin-Maricel Jureschi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jorge Linares
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Pierre Richard Dahoo
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yann Garcia
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Aurelian Rotaru
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jorge Linares.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chiruta, D., Jureschi, CM., Linares, J. et al. On the origin of multi-step spin transition behaviour in 1D nanoparticles. Eur. Phys. J. B 88, 233 (2015). https://doi.org/10.1140/epjb/e2015-60340-x

Download citation

  • Received:

  • Revised:

  • Published:

  • DOI: https://doi.org/10.1140/epjb/e2015-60340-x

Keywords

Search

Navigation