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Metalorganic Catalysts for Synthesis and Polymerization

Recent Results by Ziegler-Natta and Metallocene Investigations

  • Conference proceedings
  • © 1999

Overview

Editors:
  1. Walter Kaminsky

    1. Institute for Technical and Macromolecular Chemistry, University of Hamburg, Hamburg, Germany

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  • Metalorganic Catalysts are not only still used but have recently become again more and more important for synthesis and polymerization
  • These up-to-date research results are very important to the scientific community

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Table of contents (60 papers)

  1. Front Matter

    Pages I-XIII
    Download chapter PDF

  2. Hetrogeneous Ziegler-Natta Catalysis

    1. Front Matter

      Pages 1-1
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    2. Polyethylene: Polymer with Future

      • L. L. Böhm, J. Berthold, H.-F. Enderle, M. Fleissner
      Pages 3-13

    3. Polypropylene: 44 Years Young! The Challenge for the 21st Century

      • P. Galli, G. Cecchin, J. C. Chadwick, D. Del Duca, G. Vecellio
      Pages 14-29

    4. Characterization of PP prepared with the latest metallocene and MgCl2-supported TiCl4 catalyst systems

      • Norio Kashiwa, Shin-ichi Kojoh, Jun-ichi Imuta, Toshiyuki Tsutsui
      Pages 30-37

    5. An Absolute Test of Rival Theories for MWDs in Heterogeneous Polymerization-MWDs during Quasi-Living Polymerization

      • Tominaga Keii, Teruo Matsuzawa
      Pages 38-49

    6. Olefin Polymerization with Novel Type of Ziegler Catalysts

      • Kazuo Soga, Eiichi Kaji, Toshiya Uozumi
      Pages 50-59

    7. Kinetics and Mechanism of Ethylene Polymerization and Copolymerization Reactions with Heterogeneous Titanium-Based Ziegler-Natta Catalysts

      • Yury V. Kissin, Robert I. Mink, Thomas E. Nowlin, Anita J. Brandolini
      Pages 60-75

    8. New insight into propene polymerization promoted by heterogeneous Ziegler-Natta catalysts

      • Vincenzo Busico, Roberta Cipullo, Guglielmo Monaco, Giovanni Talarico, Michele Vacatello, John C. Chadwick et al.
      Pages 76-88

    9. Energy Distribution of Active Sites in Heterogeneous Ziegler-Natta Catalysts. Method of Study of Active Site Non-Uniformity

      • L. A. Novokshonova, N. Yu Kovaleva, Yu A. Gavrilov, V. G. Krasheninnikov, T. A. Ladygin, I. O. Leipunskii et al.
      Pages 89-96

    10. Ziegler-Natta and Metallocene Polymerisation of Olefins with Heterogeneous Catalysts

      • Karin Weiss, Sandra Botzenhardt, Monika Hofmann
      Pages 97-101

  3. Homogeneous Catalysis, Synthesis and Polymerization

    1. Front Matter

      Pages 103-103
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    2. Formation, structure and mechanism of oligomeric methylaluminoxanes (MAO)

      • Hansjörg Sinn, Ingrid Schimmel, Mathias Ott, Norbert von Thienen, Annette Harder, Wiebke Hagendorf et al.
      Pages 105-122

    3. The Activation of Metal-Fluorine Bonds in Compounds of Group 4 by Aluminum Alkyls

      • Helge Wessel, Axel Herzog, Peihua Yu, Herbert W. Roesky
      Pages 123-127

    4. A DFT quantum-chemical study of the structures and reactive sites of polymethylalumoxane

      • Ivan I. Zakharov, Vladimir A. Zakharov, Georgii M. Zhidomirov
      Pages 128-135

    5. In situ FTIR spectroscopy shows no evidence of reaction between MAO and TMA

      • Jan L. Eilertsen, Erling Rytter, Martin Ystenes
      Pages 136-141

    6. Alumoxanes alternative to MAO: Synthesis and characterization

      • T. Dall’Occo, M. Galimberti, I. Camurati, M. Destro, O. Fusco, D. Brita
      Pages 142-149

    7. Expanding the Scope of Metallocene Catalysis: Beyond Indenyl and Fluorenyl Derivatives

      • John A. Ewen, Robert L. Jones, Michael J. Elder
      Pages 150-169

    8. New C1-Symmetric Metallocenes for the Polymerization of Olefins

      • Walter Kaminsky, Ralf Werner
      Pages 170-179

    9. New Catalyst Concepts for the Polymerization of Ethylene with Metallocenes

      • A. Akimoto, A. Yano
      Pages 180-191
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Keywords

About this book

45 years after the discovery of transition metals and organometallics as cocatalysts for the polymerization of olefins and for organic synthesis, these compounds have not lost their fascination. The birthday of Karl Ziegler, the great pioneer in this metalorganic catalysis, is now 100 years ago. Polyolefins and polydienes produced by Ziegler-Natta catalysis are the most important plastics and elastomers. New impulses for the polymerization of olefins have been brought about by highly active metallocenes and other single site catalysts. Just by changing the ligands of the organometallic compounds, the structure of the polymers produced can be tailored in a wide manner. In invited lectures and posters, relevant aspects of the metalorganic catalysts for synthesis and polymerization are discussed in this book. This includes mechanism and kinetics, stereochemistry, material properties, and industrial applications.

Editors and Affiliations

  • Institute for Technical and Macromolecular Chemistry, University of Hamburg, Hamburg, Germany

    Walter Kaminsky

Bibliographic Information

  • Book Title: Metalorganic Catalysts for Synthesis and Polymerization

  • Book Subtitle: Recent Results by Ziegler-Natta and Metallocene Investigations

  • Editors: Walter Kaminsky

  • DOI: https://doi.org/10.1007/978-3-642-60178-1

  • Publisher: Springer Berlin, Heidelberg

  • eBook Packages: Springer Book Archive

  • Copyright Information: Springer-Verlag Berlin Heidelberg 1999

  • Hardcover ISBN: 978-3-540-65813-9Due: 01 June 1999

  • Softcover ISBN: 978-3-642-64292-0Published: 15 November 2011

  • eBook ISBN: 978-3-642-60178-1Published: 06 December 2012

  • Edition Number: 1

  • Number of Pages: XIII, 674

  • Topics: Polymer Sciences, Industrial Chemistry/Chemical Engineering, Organic Chemistry, Inorganic Chemistry

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