Abstract
A recently proposed theory for a single excited state based on Kato’s theorem is reviewed. The concept of adiabatic connection is extended and the validity of Kato’s theorem along the adiabatic path is discussed. Exchange identities are derive dutilizing the principle of adiabatic connection and coordinate scaling. A generalized ‘Koopmans’ theorem’ is derived.
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Nagy, Á. (2001). Theory of Exact Exchange Relations for a Single Excited State. In: New Trends in Quantum Systems in Chemistry and Physics. Progress in Theoretical Chemistry and Physics, vol 6. Springer, Dordrecht. https://doi.org/10.1007/0-306-46951-0_2
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DOI: https://doi.org/10.1007/0-306-46951-0_2
Publisher Name: Springer, Dordrecht
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