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DEFECT ENERGY LEVELS IN HIGH-K GATE OXIDES

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Defects in High-k Gate Dielectric Stacks

Part of the book series: NATO Science Series II: Mathematics, Physics and Chemistry ((NAII,volume 220))

Abstract

We present calculations of the electrical energy levels of the oxygen vacancy and the oxygen interstitial in HfO2, ZrO2, ZrSiO4 and La2O3. The levels are aligned to those of the Si channel using the known band offsets. In HfO2, the oxygen vacancy gives an energy level in the Si gap or just above the gap, depending on its charge state. This is the main electrically active defect and trap. The oxygen interstitial gives levels just above the oxide valence band, and the neutral interstitial also gives a level near the Si conduction band.

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References

  1. G Wilk, R M Wallace, J M Anthony, J App Phys 89 5243 (2001)

    Google Scholar 

  2. J Robertson, Euro Phys J Appl Phys 28 265(2004)

    Google Scholar 

  3. H J Hubbard, D G Schlom, J Mater Res 11 2757 (1996)

    Google Scholar 

  4. J Robertson, J Vac Sci Technol B 18 1785 (2000)

    Article  Google Scholar 

  5. E P Gusev, et al, Tech Digest–IEDM (2001) p455

    Google Scholar 

  6. LA Ragnarsson, S Guha, M Copel, E Cartier, N A Bojarczuk, J Karasinski, App Phys Lett 78 4169 (2001)

    Article  Google Scholar 

  7. G Bersuker, P Zeitzoff, G Brown, H R Huff, Mats Today 7 (Jan 2004)

    Google Scholar 

  8. S Zafar, A Callegari, E Gusev, M Fischetti, J App Phys 93 9298 (2003)

    Google Scholar 

  9. A Kumar, M V Fischetti, T H Ning, E Gusev, J App Phys 94 1728(2003)

    Google Scholar 

  10. A Kerber, et al, IEEE ED Lett 24 87(2003)

    Google Scholar 

  11. A Shanware, et al, Tech Digest IEDM (2003) paper 38-6

    Google Scholar 

  12. M V Fischetti, D A Neumayer, E A Cartier, J App Phys 90 4587 (2001)

    Google Scholar 

  13. Z Ren, M V Fischetti, E P Gusev, E A Cartier, M Chudzik, Tech Digest IEDM (2003) paper 33.2

    Google Scholar 

  14. R Chau, S Datta, M Doczy, B Doyle, J Kavalieros, M Metz, IEEE ED Letts 25 408 (2004)

    Google Scholar 

  15. W J Zhu, T P Ma, IEEE ED Letts 25 89 (2004)

    Google Scholar 

  16. C Hobbs, et al, VLSI Symp (2003) p9

    Google Scholar 

  17. A Y Kang, P M Lenahan, J F Conley, App Phys Lett 83 3407 (2003);

    Google Scholar 

  18. P M Lenahan, J F Conley, IEEE Trans EDM Reliab 5 90 (2005)

    Google Scholar 

  19. A S Foster, V B Sulimov, F L Gejo, A L Shluger, R N Nieminen, Phys Rev B 64 224108 (2001)

    Google Scholar 

  20. A S Foster, F L Gejo, A L Shluger, R N Nieminen, Phys Rev B 65 174117 (2002)

    Google Scholar 

  21. K Torii, et al, Tech Digest IEDM (2004) p 129

    Google Scholar 

  22. C Shen et al, Tech Digest IEDM (2004) p733

    Google Scholar 

  23. J Kang, E C Lee, K J Chang, Y G Jin, App Phys Lett 84 3894 (2004)

    Google Scholar 

  24. C Shen, et al, App Phys Lett 86 093510 (2005)

    Google Scholar 

  25. J L Gavartin, et al, Microelectronic Eng 80 412(2005)

    Article  Google Scholar 

  26. B Kralik, E K Chang, S G Louie, Phys Rev B 57 7027 (1998)

    Google Scholar 

  27. V Milman, B Winkler, J A White, C J Pickard, M C Payne, Int J Quantum Chem 77 895 (2000)

    Article  Google Scholar 

  28. P W Peacock, J Robertson, J App Phys 92 4712 (2002)

    Google Scholar 

  29. P W Peacock, J Robertson, Phys Rev Letts 92 057601 (2004)

    Article  Google Scholar 

  30. J Robertson, P W Peacock, Phys Stat Solid B 241 2236 (2004)

    Google Scholar 

  31. J Muscat, A Wander, N M Harrison, Chem Phys Lett 342 397 (2001)

    Article  Google Scholar 

  32. B M Bylander, L Kleinman, Phys Rev B 41 7868 (1990)

    Google Scholar 

  33. A Seidl, A Gorling, P Vogl, J A Majewski, M Levy, Phys Rev B 53 3764 (1996)

    Article  Google Scholar 

  34. C B Geller, et al, App Phys Lett 79 368 (2001)

    Article  Google Scholar 

  35. P P Rushton, D J Tozer, S J Clark, Phys Rev B 65 235203 (2002)

    Google Scholar 

  36. S Sayan, E Garfunkel, S Suzer, App Phys Lett 80 2135 (2002)

    Article  Google Scholar 

  37. E P O’ Reilly, J. Robertson, Phys Rev B 27 3780 (1983)

    Google Scholar 

  38. T Hattori, et al, Microelect Eng 72 283 (2004)

    Google Scholar 

  39. H Takeuchi, D Ha, T J King, J Vac Sci Technol A 22 1337 (2004)

    Article  Google Scholar 

  40. C Z Zhao, M B Zahid, J F Zhang, G Groesenken, R Degraeve, S DeGendt, Microelectronic Eng 80 366 (2005)

    Article  Google Scholar 

  41. M Houssa, M Touminen, M Naili, V Afanasev, A Stesmans, S Haukka, M M Heyns, J App Phys 87 8615 (2000)

    Google Scholar 

  42. H Kim, A Marshall, P C McIntyre, K C Saraswat, App Phys Lett 84 2064 (2004)

    Google Scholar 

  43. E P Gusev et al, Tech Digest IEDM (2004) p729

    Google Scholar 

  44. F C Chiu, H W Chou, Y M Lee, J App Phys 97 103503 (2005)

    Google Scholar 

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ROBERTSON, J., XIONG, K., CLARK, S., CLARK, S. (2006). DEFECT ENERGY LEVELS IN HIGH-K GATE OXIDES. In: Gusev, E. (eds) Defects in High-k Gate Dielectric Stacks. NATO Science Series II: Mathematics, Physics and Chemistry, vol 220. Springer, Dordrecht. https://doi.org/10.1007/1-4020-4367-8_14

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  • DOI: https://doi.org/10.1007/1-4020-4367-8_14

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-4365-9

  • Online ISBN: 978-1-4020-4367-3

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