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Uranyl photophysics

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Topics in Inorganic and Physical Chemistry

Part of the book series: Structure and Bonding ((STRUCTURE,volume 50))

Abstract

The electron transfer bands of the triatomic uranyl group are due to a complicated manifold of excited levels described by relativistic effects in linear symmetry. The lowest of these levels can live for longer than 1 millisecond (in the absence of adjacent hydrogen atoms) and has its own chemistry, reacting with many anions, univalent silver and thallium, in a way entirely different from the groundstate. It is nearly as oxidizing as free fluorine; forms exciplexes; and abstracts hydrogen atoms from organic molecules (perhaps also in the ocean) and from water. The spectroscopic and luminescent properties are compared with the hexafluorides and the dioxo complexes of quinquevalent and sexivalent uranium, neptunium, plutonium and americium, and with roughly octahedral species, and tungstates. Uranyl glasses are useful for energy transfer to lanthanides and converting solar energy via photovoltaics.

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Authors and Affiliations

  1. Département de Chimie minérale, analytique et appliquée, Université de Genève, CH 1211, Geneva 4, Switzerland

    Christian K. Jørgensen

  2. Department of Inorganic and Analytical Chemistry, and the Energy Center, Hebrew University, Jerusalem, Israel

    Renata Reisfeld

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  1. Christian K. Jørgensen
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Enrique Berman professor of solar energy

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Jørgensen, C.K., Reisfeld, R. (1982). Uranyl photophysics. In: Topics in Inorganic and Physical Chemistry. Structure and Bonding, vol 50. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-11454-8_4

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